"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications

Masayuki Okajima; Seiji Suga; Kenichiro Itami; Jun Ichi Yoshida

doi:10.1021/ja050414y

"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications

Masayuki Okajima, Seiji Suga, Kenichiro Itami, Jun Ichi Yoshida

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.

Original language	English
Pages (from-to)	6930-6931
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	19
DOIs	https://doi.org/10.1021/ja050414y
Publication status	Published - May 18 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja050414y

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abstract = "The {"}cation pools{"} of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.",

author = "Masayuki Okajima and Seiji Suga and Kenichiro Itami and Yoshida, {Jun Ichi}",

year = "2005",

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T1 - "Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications

AU - Okajima, Masayuki

AU - Suga, Seiji

AU - Itami, Kenichiro

AU - Yoshida, Jun Ichi

PY - 2005/5/18

Y1 - 2005/5/18

N2 - The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.

AB - The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.

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U2 - 10.1021/ja050414y

DO - 10.1021/ja050414y

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AN - SCOPUS:18744367229

VL - 127

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 19

ER -

"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications

Abstract

ASJC Scopus subject areas

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