TY - JOUR
T1 - Cation-directed orientation of amines in ternary graphite intercalation compounds
AU - Maluangnont, Tosapol
AU - Gotoh, Kazuma
AU - Fujiwara, Kazuya
AU - Lerner, Michael M.
PY - 2011/3
Y1 - 2011/3
N2 - 1,2-Diaminopropane (1,2-DAP) provides an unusual example of an organic co-intercalate where graphite intercalation compounds (GICs) show intra-gallery orientation dependant on the identity of the alkali metal cation intercalate (Li+, Na+, or K+). The GIC gallery heights, K(1,2-DAP)yCx = 0.697 nm and Li(1,2-DAP)yC x = 0.782 nm, indicate 1,2-DAP long axis orientations that are parallel or perpendicular to the graphene sheets, respectively.
AB - 1,2-Diaminopropane (1,2-DAP) provides an unusual example of an organic co-intercalate where graphite intercalation compounds (GICs) show intra-gallery orientation dependant on the identity of the alkali metal cation intercalate (Li+, Na+, or K+). The GIC gallery heights, K(1,2-DAP)yCx = 0.697 nm and Li(1,2-DAP)yC x = 0.782 nm, indicate 1,2-DAP long axis orientations that are parallel or perpendicular to the graphene sheets, respectively.
UR - http://www.scopus.com/inward/record.url?scp=78650247734&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78650247734&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2010.10.052
DO - 10.1016/j.carbon.2010.10.052
M3 - Letter
AN - SCOPUS:78650247734
VL - 49
SP - 1040
EP - 1042
JO - Carbon
JF - Carbon
SN - 0008-6223
IS - 3
ER -