Catena-poly[[[N,N′-bis-(3-methoxy-benzyl-idene)ethyl-enediamine] copper(I)]-μ-thio-cyanato-k2 N

S]

Aliakbar Dehno Khalaji, Hassan Hadadzadeh, Kazuma Gotoh, Hiroyuki Ishida

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number1
DOIs
Publication statusPublished - 2008

Fingerprint

Copper
Cyanates
cyanates
copper
Atoms
Schiff Bases
imines
Anions
atoms
Negative ions
Ligands
anions
ligands
Dihedral angle
Chelation
Benzene
dihedral angle
benzene
Geometry
rings

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "Catena-poly[[[N,N′-bis-(3-methoxy-benzyl-idene)ethyl-enediamine] copper(I)]-μ-thio-cyanato-k2 N: S]",
abstract = "In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.",
author = "Khalaji, {Aliakbar Dehno} and Hassan Hadadzadeh and Kazuma Gotoh and Hiroyuki Ishida",
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T1 - Catena-poly[[[N,N′-bis-(3-methoxy-benzyl-idene)ethyl-enediamine] copper(I)]-μ-thio-cyanato-k2 N

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AU - Khalaji, Aliakbar Dehno

AU - Hadadzadeh, Hassan

AU - Gotoh, Kazuma

AU - Ishida, Hiroyuki

PY - 2008

Y1 - 2008

N2 - In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

AB - In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

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