Catena-poly[[[N,N′-bis-(3-methoxy-benzyl-idene)ethyl-enediamine] copper(I)]-μ-thio-cyanato-k2 N:S]

Aliakbar Dehno Khalaji, Hassan Hadadzadeh, Kazuma Gotoh, Hiroyuki Ishida

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)] n , the CuI atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.

Original languageEnglish
Pages (from-to)m70
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number1
DOIs
Publication statusPublished - Dec 1 2008

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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