Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

Hideaki Ohmura, Hayao Matsuhashi, Makoto Tanaka, Manabu Kuroboshi, Tamejiro Hiyama, Yasuo Hatanaka, Ken ichi Goda

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

Original languageEnglish
Pages (from-to)167-171
Number of pages5
JournalJournal of Organometallic Chemistry
Volume499
Issue number1-2
DOIs
Publication statusPublished - Sep 6 1995
Externally publishedYes

Keywords

  • Chirality
  • Ferrocene
  • Fluorine
  • Palladium
  • Silane
  • Silicon

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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