Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

Hideaki Ohmura; Hayao Matsuhashi; Makoto Tanaka; Manabu Kuroboshi; Tamejiro Hiyama; Yasuo Hatanaka; Ken ichi Goda

doi:10.1016/0022-328X(95)00311-D

Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

Hideaki Ohmura, Hayao Matsuhashi, Makoto Tanaka, Manabu Kuroboshi, Tamejiro Hiyama, Yasuo Hatanaka, Ken ichi Goda

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

Original language	English
Pages (from-to)	167-171
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	499
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)00311-D
Publication status	Published - Sep 6 1995
Externally published	Yes

Keywords

Chirality
Ferrocene
Fluorine
Palladium
Silane
Silicon

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane",

abstract = "A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.",

keywords = "Chirality, Ferrocene, Fluorine, Palladium, Silane, Silicon",

author = "Hideaki Ohmura and Hayao Matsuhashi and Makoto Tanaka and Manabu Kuroboshi and Tamejiro Hiyama and Yasuo Hatanaka and Goda, {Ken ichi}",

year = "1995",

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doi = "10.1016/0022-328X(95)00311-D",

language = "English",

volume = "499",

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journal = "Journal of Organometallic Chemistry",

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T1 - Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

AU - Ohmura, Hideaki

AU - Matsuhashi, Hayao

AU - Tanaka, Makoto

AU - Kuroboshi, Manabu

AU - Hiyama, Tamejiro

AU - Hatanaka, Yasuo

AU - Goda, Ken ichi

PY - 1995/9/6

Y1 - 1995/9/6

N2 - A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

AB - A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

KW - Chirality

KW - Ferrocene

KW - Fluorine

KW - Palladium

KW - Silane

KW - Silicon

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U2 - 10.1016/0022-328X(95)00311-D

DO - 10.1016/0022-328X(95)00311-D

M3 - Article

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VL - 499

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EP - 171

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1-2

ER -

Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

Abstract

Keywords

ASJC Scopus subject areas

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