Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane

Hideaki Ohmura, Hayao Matsuhashi, Makoto Tanaka, Manabu Kuroboshi, Tamejiro Hiyama, Yasuo Hatanaka, Ken ichi Goda

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

Original languageEnglish
Pages (from-to)167-171
Number of pages5
JournalJournal of Organometallic Chemistry
Volume499
Issue number1-2
Publication statusPublished - Sep 6 1995
Externally publishedYes

Fingerprint

Hydrosilylation
Silanes
dienes
silanes
Palladium
palladium
Ligands
ligands

Keywords

  • Chirality
  • Ferrocene
  • Fluorine
  • Palladium
  • Silane
  • Silicon

ASJC Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

Cite this

Ohmura, H., Matsuhashi, H., Tanaka, M., Kuroboshi, M., Hiyama, T., Hatanaka, Y., & Goda, K. I. (1995). Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane. Journal of Organometallic Chemistry, 499(1-2), 167-171.

Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane. / Ohmura, Hideaki; Matsuhashi, Hayao; Tanaka, Makoto; Kuroboshi, Manabu; Hiyama, Tamejiro; Hatanaka, Yasuo; Goda, Ken ichi.

In: Journal of Organometallic Chemistry, Vol. 499, No. 1-2, 06.09.1995, p. 167-171.

Research output: Contribution to journalArticle

Ohmura, H, Matsuhashi, H, Tanaka, M, Kuroboshi, M, Hiyama, T, Hatanaka, Y & Goda, KI 1995, 'Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane', Journal of Organometallic Chemistry, vol. 499, no. 1-2, pp. 167-171.
Ohmura H, Matsuhashi H, Tanaka M, Kuroboshi M, Hiyama T, Hatanaka Y et al. Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane. Journal of Organometallic Chemistry. 1995 Sep 6;499(1-2):167-171.
Ohmura, Hideaki ; Matsuhashi, Hayao ; Tanaka, Makoto ; Kuroboshi, Manabu ; Hiyama, Tamejiro ; Hatanaka, Yasuo ; Goda, Ken ichi. / Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane. In: Journal of Organometallic Chemistry. 1995 ; Vol. 499, No. 1-2. pp. 167-171.
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