Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Akimasa Iwado; Masaki Mifune; Jiro Kato; Junko Oda; Masahiko Chikuma; Noriko Motohashi; Yutaka Saito

doi:10.1248/cpb.48.1831

Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Akimasa Iwado, Masaki Mifune, Jiro Kato, Junko Oda, Masahiko Chikuma, Noriko Motohashi, Yutaka Saito

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O₂ in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

Original language	English
Pages (from-to)	1831-1832
Number of pages	2
Journal	Chemical and Pharmaceutical Bulletin
Volume	48
Issue number	11
DOIs	https://doi.org/10.1248/cpb.48.1831
Publication status	Published - 2000

Keywords

Immobilized metal-porphine
Oxidation catalyst
Oxidation of phenols

ASJC Scopus subject areas

Chemistry(all)
Drug Discovery

Access to Document

10.1248/cpb.48.1831

Cite this

@article{125cf615480049e59bb089e63bbd3b68,

title = "Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols",

abstract = "Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.",

keywords = "Immobilized metal-porphine, Oxidation catalyst, Oxidation of phenols",

author = "Akimasa Iwado and Masaki Mifune and Jiro Kato and Junko Oda and Masahiko Chikuma and Noriko Motohashi and Yutaka Saito",

year = "2000",

doi = "10.1248/cpb.48.1831",

language = "English",

volume = "48",

pages = "1831--1832",

journal = "Chemical and Pharmaceutical Bulletin",

issn = "0009-2363",

publisher = "Pharmaceutical Society of Japan",

number = "11",

}

TY - JOUR

T1 - Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

AU - Iwado, Akimasa

AU - Mifune, Masaki

AU - Kato, Jiro

AU - Oda, Junko

AU - Chikuma, Masahiko

AU - Motohashi, Noriko

AU - Saito, Yutaka

PY - 2000

Y1 - 2000

N2 - Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

AB - Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

KW - Immobilized metal-porphine

KW - Oxidation catalyst

KW - Oxidation of phenols

UR - http://www.scopus.com/inward/record.url?scp=0033661865&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033661865&partnerID=8YFLogxK

U2 - 10.1248/cpb.48.1831

DO - 10.1248/cpb.48.1831

M3 - Article

C2 - 11086930

AN - SCOPUS:0033661865

VL - 48

SP - 1831

EP - 1832

JO - Chemical and Pharmaceutical Bulletin

JF - Chemical and Pharmaceutical Bulletin

SN - 0009-2363

IS - 11

ER -

Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this