Abstract
Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.
| Original language | English |
|---|---|
| Pages (from-to) | 1831-1832 |
| Number of pages | 2 |
| Journal | Chemical and Pharmaceutical Bulletin |
| Volume | 48 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Jan 1 2000 |
Keywords
- Immobilized metal-porphine
- Oxidation catalyst
- Oxidation of phenols
ASJC Scopus subject areas
- Chemistry(all)
- Drug Discovery
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Cite this
Iwado, A., Mifune, M., Kato, J., Oda, J., Chikuma, M., Motohashi, N., & Saito, Y. (2000). Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols. Chemical and Pharmaceutical Bulletin, 48(11), 1831-1832. https://doi.org/10.1248/cpb.48.1831