Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Akimasa Iwado, Masaki Mifune, Jiro Kato, Junko Oda, Masahiko Chikuma, Noriko Motohashi, Yutaka Saito

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

Original languageEnglish
Pages (from-to)1831-1832
Number of pages2
JournalChemical and Pharmaceutical Bulletin
Volume48
Issue number11
DOIs
Publication statusPublished - Jan 1 2000

Keywords

  • Immobilized metal-porphine
  • Oxidation catalyst
  • Oxidation of phenols

ASJC Scopus subject areas

  • Chemistry(all)
  • Drug Discovery

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