Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Akimasa Iwado; Masaki Mifune; Jiro Kato; Junko Oda; Masahiko Chikuma; Noriko Motohashi; Yutaka Saito

doi:10.1248/cpb.48.1831

Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

Akimasa Iwado, Masaki Mifune, Jiro Kato, Junko Oda, Masahiko Chikuma, Noriko Motohashi, Yutaka Saito

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O₂ in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

Original language	English
Pages (from-to)	1831-1832
Number of pages	2
Journal	Chemical and Pharmaceutical Bulletin
Volume	48
Issue number	11
DOIs	https://doi.org/10.1248/cpb.48.1831
Publication status	Published - 2000

Keywords

Immobilized metal-porphine
Oxidation catalyst
Oxidation of phenols

ASJC Scopus subject areas

Chemistry(all)
Drug Discovery

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title = "Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols",

abstract = "Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.",

keywords = "Immobilized metal-porphine, Oxidation catalyst, Oxidation of phenols",

author = "Akimasa Iwado and Masaki Mifune and Jiro Kato and Junko Oda and Masahiko Chikuma and Noriko Motohashi and Yutaka Saito",

year = "2000",

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T1 - Catalytic activity of anion-exchange resins modified with metal-porphine in oxidative reactions of phenols

AU - Iwado, Akimasa

AU - Mifune, Masaki

AU - Kato, Jiro

AU - Oda, Junko

AU - Chikuma, Masahiko

AU - Motohashi, Noriko

AU - Saito, Yutaka

PY - 2000

Y1 - 2000

N2 - Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

AB - Anion-exchange resins modified with metal-porphine (M-P(r)) have been investigated to develop a solid catalyst in the oxidative reaction of phenols by O2 in air. Co-P(r), which is easily prepared and separable from the reaction mixture, has been proved to accelerate the oxidative reaction of phenols such as 3,5-di-tert-butyl-4-hydroxyanisole. The resulting main oxidative products were identified to be quinones by using the GC-MS method.

KW - Immobilized metal-porphine

KW - Oxidation catalyst

KW - Oxidation of phenols

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