Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journalArticle

78 Citations (Scopus)

Abstract

Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

Original languageEnglish
Pages (from-to)2531-2534
Number of pages4
JournalTetrahedron Letters
Volume21
Issue number26
DOIs
Publication statusPublished - 1980
Externally publishedYes

Fingerprint

Alkenylation
Alkylation
Palladium
Carbon Monoxide
Phosphates

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex. / Takai, Kazuhiko; Oshima, Koichiro; Nozaki, Hitosi.

In: Tetrahedron Letters, Vol. 21, No. 26, 1980, p. 2531-2534.

Research output: Contribution to journalArticle

@article{291f1627886b4baebcfef6bcffc686ad,
title = "Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex",
abstract = "Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.",
author = "Kazuhiko Takai and Koichiro Oshima and Hitosi Nozaki",
year = "1980",
doi = "10.1016/0040-4039(80)80120-1",
language = "English",
volume = "21",
pages = "2531--2534",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "26",

}

TY - JOUR

T1 - Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

AU - Takai, Kazuhiko

AU - Oshima, Koichiro

AU - Nozaki, Hitosi

PY - 1980

Y1 - 1980

N2 - Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

AB - Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

UR - http://www.scopus.com/inward/record.url?scp=0012152398&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0012152398&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(80)80120-1

DO - 10.1016/0040-4039(80)80120-1

M3 - Article

AN - SCOPUS:0012152398

VL - 21

SP - 2531

EP - 2534

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 26

ER -