Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journalArticle

82 Citations (Scopus)

Abstract

Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

Original languageEnglish
Pages (from-to)2531-2534
Number of pages4
JournalTetrahedron Letters
Volume21
Issue number26
DOIs
Publication statusPublished - 1980
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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