Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai; Koichiro Oshima; Hitosi Nozaki

doi:10.1016/0040-4039(80)80120-1

Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh₃)₄. Alkenylation and alkynylation are also described.

Original language	English
Pages (from-to)	2531-2534
Number of pages	4
Journal	Tetrahedron Letters
Volume	21
Issue number	26
DOIs	https://doi.org/10.1016/0040-4039(80)80120-1
Publication status	Published - 1980
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex",

abstract = "Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.",

author = "Kazuhiko Takai and Koichiro Oshima and Hitosi Nozaki",

year = "1980",

doi = "10.1016/0040-4039(80)80120-1",

language = "English",

volume = "21",

pages = "2531--2534",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

AU - Takai, Kazuhiko

AU - Oshima, Koichiro

AU - Nozaki, Hitosi

PY - 1980

Y1 - 1980

N2 - Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

AB - Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

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U2 - 10.1016/0040-4039(80)80120-1

DO - 10.1016/0040-4039(80)80120-1

M3 - Article

AN - SCOPUS:0012152398

VL - 21

SP - 2531

EP - 2534

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 26

ER -