Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai; Koichiro Oshima; Hitosi Nozaki

doi:10.1016/0040-4039(80)80120-1

Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex

Kazuhiko Takai, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journal › Article

79 Citations (Scopus)

Abstract

Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh₃)₄. Alkenylation and alkynylation are also described.

Original language	English
Pages (from-to)	2531-2534
Number of pages	4
Journal	Tetrahedron Letters
Volume	21
Issue number	26
DOIs	https://doi.org/10.1016/0040-4039(80)80120-1
Publication status	Published - 1980

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ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Cite this

Takai, K., Oshima, K., & Nozaki, H. (1980). Carboncarbon bond formation by cross-coupling of enol phosphates with organoaluminium compounds catalyzed by palladium(O) complex. Tetrahedron Letters, 21(26), 2531-2534. https://doi.org/10.1016/0040-4039(80)80120-1

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abstract = "Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.",

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PY - 1980

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AB - Trialkylaluminium-mediated alkylation of enol phosphates under the CO bond cleavage is performed stereospecifically in the presence of a catalytic amount of Pd(PPh3)4. Alkenylation and alkynylation are also described.

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Access to Document

10.1016/0040-4039(80)80120-1