Abstract
Physical modifications of single-walled carbon nanotubes (SWCNTs) with fullerodendrons, followed by complexation with RuCl3 leads to the formation of CNT-photocatalysts that exhibit high quantum yields (QY = 12.8%) for the production of H2 from water, even under illumination with NIR light (λirr = 1005 nm) in the presence of sacrificial donor. A Z-scheme photocatalytic system, consisting of such a CNT-photocatalyst, BiVO4, and [Co(bpy)3]3+/2+ shows a production of H2 (17 μmol/h) and O2 (5.5μmol/h) under illumination from a solar simulator (AM-1.5) with a solar-to-hydrogen (STH) efficiency of 0.089%.
Original language | English |
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Pages (from-to) | 410-413 |
Number of pages | 4 |
Journal | Chemistry Letters |
Volume | 48 |
Issue number | 5 |
DOIs | |
Publication status | Published - 2019 |
Keywords
- Carbon nanotube
- Photocatalyst
- Water-splitting
ASJC Scopus subject areas
- Chemistry(all)