CaCu3Ti4O12-type colossal dielectric relaxation in complex perovskite (Ba1-xLax)(Ti 1-xCrx)O3

Mamoru Fukunaga, Yoshiaki Uesu, Guobao Li

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Dielectric constants of complex perovskite oxide (Ba1-xLa x)(Ti1-xCrx)O3 (BLTC) ceramics with 0.4≤x≤0.7 are measured, and a remarkable colossal dielectric relaxation which is quite similar to that of CaCu3Ti4O12 (CCTO) is found in higher temperature region above the ferroelectric phase transition. This kind of dielectric relaxation is successfully explained by an equivalent circuit model of a series of two R-C parallel circuits with temperature-dependent electrical conductivity and temperature-independent intrinsic dielectric constant. It is also found that the dc bias effect on the sample can distinguish this hetero-structure model and the proper Debye relaxation model of a homogeneous phase.

Original languageEnglish
Pages (from-to)106-114
Number of pages9
JournalFerroelectrics
Volume354
Issue number1
DOIs
Publication statusPublished - 2007
Externally publishedYes

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Dielectric relaxation
Perovskite
Permittivity
permittivity
Model structures
equivalent circuits
Equivalent circuits
Temperature
Oxides
Ferroelectric materials
Phase transitions
ceramics
electrical resistivity
temperature
oxides
Networks (circuits)
perovskite

Keywords

  • (BaLa)(TiCr )O
  • CaCuTiO
  • Colossal dielectric relaxation
  • Dielectrics
  • Hetero-structure model

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

CaCu3Ti4O12-type colossal dielectric relaxation in complex perovskite (Ba1-xLax)(Ti 1-xCrx)O3. / Fukunaga, Mamoru; Uesu, Yoshiaki; Li, Guobao.

In: Ferroelectrics, Vol. 354, No. 1, 2007, p. 106-114.

Research output: Contribution to journalArticle

Fukunaga, Mamoru ; Uesu, Yoshiaki ; Li, Guobao. / CaCu3Ti4O12-type colossal dielectric relaxation in complex perovskite (Ba1-xLax)(Ti 1-xCrx)O3. In: Ferroelectrics. 2007 ; Vol. 354, No. 1. pp. 106-114.
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