C-C and C-H bond activation of dialkylmethylenecyclopropane promoted by rhodium and iridium complexes. Preparation and structures of M(η12-CH2CR2CH=CH 2)(CO)(PPh3)2 and trans-M(CH=CHCMeR 2)(CO)(PPh3)2 (M = Rh, Ir, R = CH 2CH2Ph)

Masumi Itazaki, Chikako Yoda, Yasushi Nishihara, Kohtaro Osakada

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Dive into the research topics of 'C-C and C-H bond activation of dialkylmethylenecyclopropane promoted by rhodium and iridium complexes. Preparation and structures of M(η<sup>1</sup>:η<sup>2</sup>-CH<sub>2</sub>CR<sub>2</sub>CH=CH <sub>2</sub>)(CO)(PPh<sub>3</sub>)<sub>2</sub> and trans-M(CH=CHCMeR <sub>2</sub>)(CO)(PPh<sub>3</sub>)<sub>2</sub> (M = Rh, Ir, R = CH <sub>2</sub>CH<sub>2</sub>Ph)'. Together they form a unique fingerprint.

Physics & Astronomy

Chemical Compounds