Bulk electronic structure of Na0.35CoO2·1. 3H2O

A. Chainani, T. Yokoya, Y. Takata, K. Tamasaku, M. Taguchi, T. Shimojima, N. Kamakura, K. Horiba, S. Tsuda, S. Shin, D. Miwa, Y. Nishino, T. Ishikawa, M. Yabashi, K. Kobayashi, H. Namatame, M. Taniguchi, K. Takada, T. Sasaki, H. SakuraiE. Takayama-Muromachi

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48 Citations (Scopus)

Abstract

High-energy (hv = 5.95 keV) synchrotron photoemission spectroscopy (PES) is used to study bulk electronic structure of Na0.35CoO2 · 1.3H2O, the layered superconductor. In contrast to three-dimensional doped Co oxides, Co 2p core level spectra show well-separated Co3+ and Co4+ ions. Cluster calculations suggest low-spin Co3+ and Co4+ character, and a moderate on-site Coulomb correlation energy Udd∼3-5.5 eV. Photon dependent valence band PES identifies Co 3d and O 2p derived states, in near agreement with band-structure calculations.

Original languageEnglish
Article number180508
Pages (from-to)180508-1-180508-4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume69
Issue number18
DOIs
Publication statusPublished - May 1 2004
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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    Chainani, A., Yokoya, T., Takata, Y., Tamasaku, K., Taguchi, M., Shimojima, T., Kamakura, N., Horiba, K., Tsuda, S., Shin, S., Miwa, D., Nishino, Y., Ishikawa, T., Yabashi, M., Kobayashi, K., Namatame, H., Taniguchi, M., Takada, K., Sasaki, T., ... Takayama-Muromachi, E. (2004). Bulk electronic structure of Na0.35CoO2·1. 3H2O. Physical Review B - Condensed Matter and Materials Physics, 69(18), 180508-1-180508-4. [180508]. https://doi.org/10.1103/PhysRevB.69.180508