Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation

Yuta Nishina, Bunsho Ohtani, Kotaro Kikushima

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The bromination of hydrocarbons with CBr4 as a bromine source, induced by light-emitting diode (LED) irradiation, has been developed. Monobromides were synthesized with high efficiency without the need for any additives, catalysts, heating, or inert conditions. Action and absorption spectra suggest that CBr4 absorbs light to give active species for the bromination. The generation of CHBr3 was confirmed by NMR spectroscopy and GC-MS spectrometry analysis, indicating that the present bromination involves the homolytic cleavage of a C-Br bond in CBr4 followed by radical abstraction of a hydrogen atom from a hydrocarbon.

Original languageEnglish
Pages (from-to)1663-1667
Number of pages5
JournalBeilstein Journal of Organic Chemistry
Volume9
DOIs
Publication statusPublished - Aug 14 2013

Keywords

  • Bromination
  • Free radical
  • Hydrocarbon
  • Light-emitting diode
  • Photo irradiation

ASJC Scopus subject areas

  • Organic Chemistry

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