Bright greenish-yellow pigments based on Sc2− xFexO3 solid solutions with bixbyite structure

Hideki Hashimoto, Kotaro Sayo, Hidetaka Asoh, Tatsuo Fujii, Mikio Takano, Atsunobu Masuno

Research output: Contribution to journalArticle

Abstract

An oxide system Sc2− xFexO3 prepared by a conventional solid-state reaction method was found to change its color from the well-known reddish color at x = 2.0 to a yellowish color at x ≈ 0.6 and to a greenish-yellow color at 0.2 ≤ x ≤ 0.4. According to the structural characterization results for this system, the monophasic corundum phase region persists for 1.6 ≤ x ≤ 2.0, whereas the bixbyite-type phase is monophasic for 0 ≤ x ≤ 1.0. The intermediate region of 1.2 ≤ x ≤ 1.4 is a mixed region. Because green is a rare color for iron oxides, powder of the most typical composition, x = 0.4, with (L*, a*, b*) coordinates of (77.3, −0.5, 51.0) was tested as a pigment for a Japanese-style painting and also as an overglaze enamel on porcelain; reasonably good results were obtained.

LanguageEnglish
Pages190-194
Number of pages5
JournalMaterials Research Bulletin
Volume109
DOIs
Publication statusPublished - Jan 1 2019

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pigments
Pigments
Solid solutions
solid solutions
Color
color
porcelain
Dental Porcelain
Corundum
enamels
Porcelain
Enamels
Aluminum Oxide
Painting
Solid state reactions
Iron oxides
iron oxides
Powders
Oxides
aluminum oxides

Keywords

  • Fe Mӧssbauer spectroscopy
  • Color measurements
  • Pigments

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Bright greenish-yellow pigments based on Sc2− xFexO3 solid solutions with bixbyite structure. / Hashimoto, Hideki; Sayo, Kotaro; Asoh, Hidetaka; Fujii, Tatsuo; Takano, Mikio; Masuno, Atsunobu.

In: Materials Research Bulletin, Vol. 109, 01.01.2019, p. 190-194.

Research output: Contribution to journalArticle

Hashimoto, Hideki ; Sayo, Kotaro ; Asoh, Hidetaka ; Fujii, Tatsuo ; Takano, Mikio ; Masuno, Atsunobu. / Bright greenish-yellow pigments based on Sc2− xFexO3 solid solutions with bixbyite structure. In: Materials Research Bulletin. 2019 ; Vol. 109. pp. 190-194.
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