Bridging the gap between small clusters and nanodroplets: Spectroscopic study and computer simulation of carbon dioxide solvated with helium atoms

J. Tang, A. R.W. McKellar, F. Mezzacapo, S. Moroni

Research output: Contribution to journalArticle

99 Citations (Scopus)

Abstract

The high resolution infrared spectra of HeN-CO2 cluster with N up to 17 in the region of the CO2 v3 fundamental band was studied. The He density profiles for HeN-CO 2 with N=5 and 6 were compared with those of HeN-carbonyl sulfide (OCS) and HeN-N2O. The variation of the vibrational band origin, vO, with cluster size, which includes a comparison with HeN-OCS and HeN-N2O, was also shown. The measured and calculated values of the rotational constant B and centrifugal distortion D were also compared.

Original languageEnglish
Article number145503
Pages (from-to)145503-1-145503-4
JournalPhysical Review Letters
Volume92
Issue number14
DOIs
Publication statusPublished - Apr 9 2004

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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