Bridging the gap between small clusters and nanodroplets: Spectroscopic study and computer simulation of carbon dioxide solvated with helium atoms

Jian Tang, A. R W McKellar, F. Mezzacapo, S. Moroni

Research output: Contribution to journalArticle

100 Citations (Scopus)

Abstract

The high resolution infrared spectra of HeN-CO2 cluster with N up to 17 in the region of the CO2 v3 fundamental band was studied. The He density profiles for HeN-CO 2 with N=5 and 6 were compared with those of HeN-carbonyl sulfide (OCS) and HeN-N2O. The variation of the vibrational band origin, vO, with cluster size, which includes a comparison with HeN-OCS and HeN-N2O, was also shown. The measured and calculated values of the rotational constant B and centrifugal distortion D were also compared.

Original languageEnglish
Pages (from-to)145503-145501
Number of pages3
JournalPhysical Review Letters
Volume92
Issue number14
DOIs
Publication statusPublished - Apr 9 2004
Externally publishedYes

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helium atoms
carbon dioxide
sulfides
computerized simulation
infrared spectra
simulation
high resolution
profiles

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Bridging the gap between small clusters and nanodroplets : Spectroscopic study and computer simulation of carbon dioxide solvated with helium atoms. / Tang, Jian; McKellar, A. R W; Mezzacapo, F.; Moroni, S.

In: Physical Review Letters, Vol. 92, No. 14, 09.04.2004, p. 145503-145501.

Research output: Contribution to journalArticle

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