Brønsted base-assisted boronic acid catalysis for the dehydrative intramolecular condensation of dicarboxylic acids

Akira Sakakura; Takuro Ohkubo; Risa Yamashita; Matsujiro Akakura; Kazuaki Ishihara

doi:10.1021/ol102926n

Brønsted base-assisted boronic acid catalysis for the dehydrative intramolecular condensation of dicarboxylic acids

Akira Sakakura, Takuro Ohkubo, Risa Yamashita, Matsujiro Akakura, Kazuaki Ishihara

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Brønsted base-assisted boronic acid catalysis for the dehydrative self-condensation of carboxylic acids is described. Arylboronic acid bearing bulky (N,N-dialkylamino)methyl groups at the 2,6-positions can catalyze the intramolecular dehydrative condensation of di-and tetracarboxylic acids. This is the first successful method for the catalytic dehydrative self-condensation of carboxylic acids.(Figure Presented)

Original language	English
Pages (from-to)	892-895
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	5
DOIs	https://doi.org/10.1021/ol102926n
Publication status	Published - Mar 4 2011
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol102926n

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title = "Br{\o}nsted base-assisted boronic acid catalysis for the dehydrative intramolecular condensation of dicarboxylic acids",

abstract = "Br{\o}nsted base-assisted boronic acid catalysis for the dehydrative self-condensation of carboxylic acids is described. Arylboronic acid bearing bulky (N,N-dialkylamino)methyl groups at the 2,6-positions can catalyze the intramolecular dehydrative condensation of di-and tetracarboxylic acids. This is the first successful method for the catalytic dehydrative self-condensation of carboxylic acids.(Figure Presented)",

author = "Akira Sakakura and Takuro Ohkubo and Risa Yamashita and Matsujiro Akakura and Kazuaki Ishihara",

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T1 - Brønsted base-assisted boronic acid catalysis for the dehydrative intramolecular condensation of dicarboxylic acids

AU - Sakakura, Akira

AU - Ohkubo, Takuro

AU - Yamashita, Risa

AU - Akakura, Matsujiro

AU - Ishihara, Kazuaki

PY - 2011/3/4

Y1 - 2011/3/4

N2 - Brønsted base-assisted boronic acid catalysis for the dehydrative self-condensation of carboxylic acids is described. Arylboronic acid bearing bulky (N,N-dialkylamino)methyl groups at the 2,6-positions can catalyze the intramolecular dehydrative condensation of di-and tetracarboxylic acids. This is the first successful method for the catalytic dehydrative self-condensation of carboxylic acids.(Figure Presented)

AB - Brønsted base-assisted boronic acid catalysis for the dehydrative self-condensation of carboxylic acids is described. Arylboronic acid bearing bulky (N,N-dialkylamino)methyl groups at the 2,6-positions can catalyze the intramolecular dehydrative condensation of di-and tetracarboxylic acids. This is the first successful method for the catalytic dehydrative self-condensation of carboxylic acids.(Figure Presented)

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U2 - 10.1021/ol102926n

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JO - Organic Letters

JF - Organic Letters

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Brønsted base-assisted boronic acid catalysis for the dehydrative intramolecular condensation of dicarboxylic acids

Abstract

ASJC Scopus subject areas

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