Abstract
In the crystal structure of the title compound, 2C5H6N5 +·C6Cl2O4 2-·2H2O, two adeninium cations, one chloranilate dianion and two water mol-ecules are held together by O - H⋯O, N - H⋯O, O - H⋯Cl and C - H⋯O hydrogen bonds, forming a centrosymmetric unit. The chloranilate dianion resides on an inversion centre. The anion and two cations are approximately coplanar, the dihedral angle between the planes of the adeninium cation and the chloranilate dianion being 3.25 (3)°. The crystal structure is stabilized by inter-unit N - H⋯N, N - H⋯O, N - H⋯Cl and O - H⋯N hydrogen bonds, forming a three-dimensional hydrogen-bonding network.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 63 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Oct 5 2007 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
Cite this
Bis(adeninium) chloranilate dihydrate. / Gotoh, Kazuma; Ishikawa, Rie; Ishida, Hiroyuki.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 11, 05.10.2007.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Bis(adeninium) chloranilate dihydrate
AU - Gotoh, Kazuma
AU - Ishikawa, Rie
AU - Ishida, Hiroyuki
PY - 2007/10/5
Y1 - 2007/10/5
N2 - In the crystal structure of the title compound, 2C5H6N5 +·C6Cl2O4 2-·2H2O, two adeninium cations, one chloranilate dianion and two water mol-ecules are held together by O - H⋯O, N - H⋯O, O - H⋯Cl and C - H⋯O hydrogen bonds, forming a centrosymmetric unit. The chloranilate dianion resides on an inversion centre. The anion and two cations are approximately coplanar, the dihedral angle between the planes of the adeninium cation and the chloranilate dianion being 3.25 (3)°. The crystal structure is stabilized by inter-unit N - H⋯N, N - H⋯O, N - H⋯Cl and O - H⋯N hydrogen bonds, forming a three-dimensional hydrogen-bonding network.
AB - In the crystal structure of the title compound, 2C5H6N5 +·C6Cl2O4 2-·2H2O, two adeninium cations, one chloranilate dianion and two water mol-ecules are held together by O - H⋯O, N - H⋯O, O - H⋯Cl and C - H⋯O hydrogen bonds, forming a centrosymmetric unit. The chloranilate dianion resides on an inversion centre. The anion and two cations are approximately coplanar, the dihedral angle between the planes of the adeninium cation and the chloranilate dianion being 3.25 (3)°. The crystal structure is stabilized by inter-unit N - H⋯N, N - H⋯O, N - H⋯Cl and O - H⋯N hydrogen bonds, forming a three-dimensional hydrogen-bonding network.
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U2 - 10.1107/S1600536807052087
DO - 10.1107/S1600536807052087
M3 - Article
AN - SCOPUS:35948993430
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 11
ER -