Bis(adeninium) chloranilate dihydrate

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the crystal structure of the title compound, 2C5H6N5 +·C6Cl2O4 2-·2H2O, two adeninium cations, one chloranilate dianion and two water mol-ecules are held together by O - H⋯O, N - H⋯O, O - H⋯Cl and C - H⋯O hydrogen bonds, forming a centrosymmetric unit. The chloranilate dianion resides on an inversion centre. The anion and two cations are approximately coplanar, the dihedral angle between the planes of the adeninium cation and the chloranilate dianion being 3.25 (3)°. The crystal structure is stabilized by inter-unit N - H⋯N, N - H⋯O, N - H⋯Cl and O - H⋯N hydrogen bonds, forming a three-dimensional hydrogen-bonding network.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number11
DOIs
Publication statusPublished - Oct 5 2007

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Cations
Hydrogen bonds
Positive ions
cations
Hydrogen
Crystal structure
hydrogen bonds
crystal structure
Dihedral angle
Hydrogen Bonding
Anions
dihedral angle
Negative ions
inversions
anions
Water
hydrogen
water

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis(adeninium) chloranilate dihydrate. / Gotoh, Kazuma; Ishikawa, Rie; Ishida, Hiroyuki.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 11, 05.10.2007.

Research output: Contribution to journalArticle

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