Bis[-2-(aminosulfanyl)pyridine(1-)]bis-[(5-penta-methyl-cyclo- penta-dien-yl)iridium(III)] diiodide

Yusuke Sekioka, Takayoshi Suzuki

Research output: Contribution to journalArticle

Abstract

In the title dinuclear iridium(III) complex, [Ir2(C10H15) 2(C5H5N2S)2]I2, the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1-) [(2-py)SNH] ligands in a-(2-py)SNH-2 N(py),N(NH):N(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir2N 2 ring with an Ir- N(py) bond length of 2.085 (9) Å and bridging Ir- N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with respect to the Ir2N2 ring.

Original languageEnglish
Pages (from-to)m1229-m1230
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number10
DOIs
Publication statusPublished - Oct 14 2009

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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