Bis(μ-N,N-dimethyldithiocarbamato-κ3 S,S′: S′)bis[(dimethoxyphenyl-phosphane-κP) (N,N-dimethyldithiocarbamato-κ2S,S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki, Hideo D. Takagi, Kazuo Kashiwabara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number2
DOIs
Publication statusPublished - Feb 2002
Externally publishedYes

Fingerprint

phosphine
Cobalt
cobalt
Ligands
ligands
Dimerization
dimerization
Cations
fragments
cations
Crystals
symmetry
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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title = "Bis(μ-N,N-dimethyldithiocarbamato-κ3 S,S′: S′)bis[(dimethoxyphenyl-phosphane-κP) (N,N-dimethyldithiocarbamato-κ2S,S′)cobalt(III)] bis(hexafluorophosphate)",
abstract = "Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.",
author = "Takayoshi Suzuki and Takagi, {Hideo D.} and Kazuo Kashiwabara",
year = "2002",
month = "2",
doi = "10.1107/S0108270101018406",
language = "English",
volume = "58",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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publisher = "International Union of Crystallography",
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TY - JOUR

T1 - Bis(μ-N,N-dimethyldithiocarbamato-κ3 S,S′

T2 - S′)bis[(dimethoxyphenyl-phosphane-κP) (N,N-dimethyldithiocarbamato-κ2S,S′)cobalt(III)] bis(hexafluorophosphate)

AU - Suzuki, Takayoshi

AU - Takagi, Hideo D.

AU - Kashiwabara, Kazuo

PY - 2002/2

Y1 - 2002/2

N2 - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

AB - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

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U2 - 10.1107/S0108270101018406

DO - 10.1107/S0108270101018406

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JF - Acta Crystallographica Section C: Crystal Structure Communications

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