Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki, Hideo D. Takagi, Kazuo Kashiwabara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

Original languageEnglish
Pages (from-to)m95-m97
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number2
DOIs
Publication statusPublished - Feb 2002

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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