Bis{μ-4,4′-dimeth-oxy-2,2′-[propane-1,2-diylbis(nitrilo- methyl-idyne)]diphenolato}bis-({4,4′-dimeth-oxy-2,2′-[propane-1, 2-diylbis(nitrilo-methyl-idyne)]diphenol}manganese(III)) bis-(hexa-fluorido- phosphate)

Mohammad Hossein Habibi, Elham Askari, Reza Mokhtari, Morteza Montazerozohori, Takayoshi Suzuki

Research output: Contribution to journalArticle

Abstract

In the title complex, [Mn2(C19H20N 2O4)2(C19H22N 2O4)2](PF6)2, the Mn III ion is coordinated by two O [Mn - O = 1.855 (2) and 1.887 (2) Å] and two N [Mn - N = 1.982 (3) and 1.977 (3) Å] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn - O = 2.129 (2) Å]. The centrosymmetric dimer contains two Jahn-Teller-distorted MnIII ions, each in a nearly octa-hedral geometry, connected through two phenolate bridges from two ligands. There are two stereogenic centers. The methyl group and the H atom attached to the middle propane C atom are disordered over two positions with occupancy factors in the ratio 0.58:0.42. The crystal is therefore a mixture of two diasteroisomers, viz. RS/SR and RR/SS. In the axial ligand, the two benzene rings form a dihedral angle of 56.97 (5)° and the dihedral angle between the two MnNC3O chelate rings is 2.98 (12)°

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number8
DOIs
Publication statusPublished - 2009

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Propane
Manganese
propane
manganese
phosphates
Phosphates
Ligands
ligands
Dihedral angle
Atoms
dihedral angle
Ions
atoms
Schiff Bases
rings
Benzene
chelates
Dimers
imines
ions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{19041b25950a4abf9c7de5ebd0c321c7,
title = "Bis{μ-4,4′-dimeth-oxy-2,2′-[propane-1,2-diylbis(nitrilo- methyl-idyne)]diphenolato}bis-({4,4′-dimeth-oxy-2,2′-[propane-1, 2-diylbis(nitrilo-methyl-idyne)]diphenol}manganese(III)) bis-(hexa-fluorido- phosphate)",
abstract = "In the title complex, [Mn2(C19H20N 2O4)2(C19H22N 2O4)2](PF6)2, the Mn III ion is coordinated by two O [Mn - O = 1.855 (2) and 1.887 (2) {\AA}] and two N [Mn - N = 1.982 (3) and 1.977 (3) {\AA}] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn - O = 2.129 (2) {\AA}]. The centrosymmetric dimer contains two Jahn-Teller-distorted MnIII ions, each in a nearly octa-hedral geometry, connected through two phenolate bridges from two ligands. There are two stereogenic centers. The methyl group and the H atom attached to the middle propane C atom are disordered over two positions with occupancy factors in the ratio 0.58:0.42. The crystal is therefore a mixture of two diasteroisomers, viz. RS/SR and RR/SS. In the axial ligand, the two benzene rings form a dihedral angle of 56.97 (5)° and the dihedral angle between the two MnNC3O chelate rings is 2.98 (12)°",
author = "Habibi, {Mohammad Hossein} and Elham Askari and Reza Mokhtari and Morteza Montazerozohori and Takayoshi Suzuki",
year = "2009",
doi = "10.1107/S1600536809028591",
language = "English",
volume = "65",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "8",

}

TY - JOUR

T1 - Bis{μ-4,4′-dimeth-oxy-2,2′-[propane-1,2-diylbis(nitrilo- methyl-idyne)]diphenolato}bis-({4,4′-dimeth-oxy-2,2′-[propane-1, 2-diylbis(nitrilo-methyl-idyne)]diphenol}manganese(III)) bis-(hexa-fluorido- phosphate)

AU - Habibi, Mohammad Hossein

AU - Askari, Elham

AU - Mokhtari, Reza

AU - Montazerozohori, Morteza

AU - Suzuki, Takayoshi

PY - 2009

Y1 - 2009

N2 - In the title complex, [Mn2(C19H20N 2O4)2(C19H22N 2O4)2](PF6)2, the Mn III ion is coordinated by two O [Mn - O = 1.855 (2) and 1.887 (2) Å] and two N [Mn - N = 1.982 (3) and 1.977 (3) Å] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn - O = 2.129 (2) Å]. The centrosymmetric dimer contains two Jahn-Teller-distorted MnIII ions, each in a nearly octa-hedral geometry, connected through two phenolate bridges from two ligands. There are two stereogenic centers. The methyl group and the H atom attached to the middle propane C atom are disordered over two positions with occupancy factors in the ratio 0.58:0.42. The crystal is therefore a mixture of two diasteroisomers, viz. RS/SR and RR/SS. In the axial ligand, the two benzene rings form a dihedral angle of 56.97 (5)° and the dihedral angle between the two MnNC3O chelate rings is 2.98 (12)°

AB - In the title complex, [Mn2(C19H20N 2O4)2(C19H22N 2O4)2](PF6)2, the Mn III ion is coordinated by two O [Mn - O = 1.855 (2) and 1.887 (2) Å] and two N [Mn - N = 1.982 (3) and 1.977 (3) Å] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn - O = 2.129 (2) Å]. The centrosymmetric dimer contains two Jahn-Teller-distorted MnIII ions, each in a nearly octa-hedral geometry, connected through two phenolate bridges from two ligands. There are two stereogenic centers. The methyl group and the H atom attached to the middle propane C atom are disordered over two positions with occupancy factors in the ratio 0.58:0.42. The crystal is therefore a mixture of two diasteroisomers, viz. RS/SR and RR/SS. In the axial ligand, the two benzene rings form a dihedral angle of 56.97 (5)° and the dihedral angle between the two MnNC3O chelate rings is 2.98 (12)°

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