Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

Tadashi Ema; Daisuke Tanida; Tatsuya Matsukawa; Takashi Sakai

doi:10.1039/b718763g

Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

Tadashi Ema, Daisuke Tanida, Tatsuya Matsukawa, Takashi Sakai

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

Original language	English
Pages (from-to)	957-959
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b718763g
Publication status	Published - Feb 27 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b718763g

Fingerprint Dive into the research topics of 'Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol'. Together they form a unique fingerprint.

Cite this

@article{8eda47e78be4450788ae3151c4f1a10a,

title = "Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol",

abstract = "Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.",

author = "Tadashi Ema and Daisuke Tanida and Tatsuya Matsukawa and Takashi Sakai",

year = "2008",

month = feb,

day = "27",

doi = "10.1039/b718763g",

language = "English",

pages = "957--959",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

AU - Ema, Tadashi

AU - Tanida, Daisuke

AU - Matsukawa, Tatsuya

AU - Sakai, Takashi

PY - 2008/2/27

Y1 - 2008/2/27

N2 - Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

AB - Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

UR - http://www.scopus.com/inward/record.url?scp=39549113719&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=39549113719&partnerID=8YFLogxK

U2 - 10.1039/b718763g

DO - 10.1039/b718763g

M3 - Article

C2 - 18283348

AN - SCOPUS:39549113719

SP - 957

EP - 959

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 8

ER -