Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

Tadashi Ema, Daisuke Tanida, Tatsuya Matsukawa, Takashi Sakai

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

Original languageEnglish
Pages (from-to)957-959
Number of pages3
JournalChemical Communications
Issue number8
DOIs
Publication statusPublished - 2008

Fingerprint

Hydrolases
Transesterification
Biomimetics
Serine
Catalyst activity
Esters
Alcohols
vinyl trifluoroacetate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol. / Ema, Tadashi; Tanida, Daisuke; Matsukawa, Tatsuya; Sakai, Takashi.

In: Chemical Communications, No. 8, 2008, p. 957-959.

Research output: Contribution to journalArticle

@article{8eda47e78be4450788ae3151c4f1a10a,
title = "Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol",
abstract = "Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.",
author = "Tadashi Ema and Daisuke Tanida and Tatsuya Matsukawa and Takashi Sakai",
year = "2008",
doi = "10.1039/b718763g",
language = "English",
pages = "957--959",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "8",

}

TY - JOUR

T1 - Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

AU - Ema, Tadashi

AU - Tanida, Daisuke

AU - Matsukawa, Tatsuya

AU - Sakai, Takashi

PY - 2008

Y1 - 2008

N2 - Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

AB - Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

UR - http://www.scopus.com/inward/record.url?scp=39549113719&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=39549113719&partnerID=8YFLogxK

U2 - 10.1039/b718763g

DO - 10.1039/b718763g

M3 - Article

C2 - 18283348

AN - SCOPUS:39549113719

SP - 957

EP - 959

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 8

ER -