Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

Tadashi Ema; Daisuke Tanida; Tatsuya Matsukawa; Takashi Sakai

doi:10.1039/b718763g

Biomimetic trifunctional organocatalyst showing a great acceleration for the transesterification between vinyl ester and alcohol

Tadashi Ema, Daisuke Tanida, Tatsuya Matsukawa, Takashi Sakai

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.

Original language	English
Pages (from-to)	957-959
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b718763g
Publication status	Published - Feb 27 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Trifunctional organocatalysts 1a and 1b mimicking the active site of serine hydrolases showed high catalytic activity with up to a 3 700 000-fold acceleration for the acyl-transfer reactions from vinyl trifluoroacetate to alcohol.",

author = "Tadashi Ema and Daisuke Tanida and Tatsuya Matsukawa and Takashi Sakai",

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