Biomimetic synthesis of iheyamine A from spirocyclic oxindoles

Takumi Abe; Syuhei Satake; Koji Yamada

doi:10.3987/COM-18-S(F)30

Biomimetic synthesis of iheyamine A from spirocyclic oxindoles

Takumi Abe, Syuhei Satake, Koji Yamada

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The biomimetic synthesis of azepinobisindole alkaloid iheyamine A from a spirocyclic oxindole via an oxidative rearrangement has been accomplished for the first time. Furthermore, an unprecedented method for constructing 2,1'-spirocyclic oxindoles from azepinobisindoles through an alternative oxidative rearrangement has been explored.

Original language	English
Pages (from-to)	379-388
Number of pages	10
Journal	Heterocycles
Volume	99
Issue number	1
DOIs	https://doi.org/10.3987/COM-18-S(F)30
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/COM-18-S(F)30

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title = "Biomimetic synthesis of iheyamine A from spirocyclic oxindoles",

abstract = "The biomimetic synthesis of azepinobisindole alkaloid iheyamine A from a spirocyclic oxindole via an oxidative rearrangement has been accomplished for the first time. Furthermore, an unprecedented method for constructing 2,1'-spirocyclic oxindoles from azepinobisindoles through an alternative oxidative rearrangement has been explored.",

author = "Takumi Abe and Syuhei Satake and Koji Yamada",

note = "Funding Information: This work was financially supported by JSPS (KAKENHI Grant Number 16K18849 for T.A.) as a Publisher Copyright: {\textcopyright} 2019 The Japan Institute of Heterocyclic Chemistry.",

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AU - Satake, Syuhei

AU - Yamada, Koji

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AB - The biomimetic synthesis of azepinobisindole alkaloid iheyamine A from a spirocyclic oxindole via an oxidative rearrangement has been accomplished for the first time. Furthermore, an unprecedented method for constructing 2,1'-spirocyclic oxindoles from azepinobisindoles through an alternative oxidative rearrangement has been explored.

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Biomimetic synthesis of iheyamine A from spirocyclic oxindoles

Abstract

ASJC Scopus subject areas

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