Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki-Miyaura coupling reaction

Kyoko Mandai, Toshinobu Korenaga, Tadashi Ema, Takashi Sakai, Mitsuaki Furutani, Hideki Hashimoto, Jun Takada

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Iron oxide produced by iron-oxidizing bacteria, Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields in the Suzuki-Miyaura coupling reactions under solvent-free conditions and could be reused several times without significant loss of catalytic activity. It is shown that BIO can be exploited as a useful support for immobilization of palladium and the BIO-immobilized palladium catalyst effectively promotes the solvent-free Suzuki-Miyaura coupling reactions.

Original languageEnglish
Pages (from-to)329-332
Number of pages4
JournalTetrahedron Letters
Volume53
Issue number3
DOIs
Publication statusPublished - Jan 18 2012

Fingerprint

Palladium
Catalysts
Leptothrix
Bearings (structural)
Catalyst supports
Immobilization
Catalyst activity
Bacteria
Iron
ferric oxide

Keywords

  • Biogenous iron oxide
  • Immobilized catalyst
  • Palladium catalyst
  • Solvent-free reaction
  • Suzuki-Miyaura coupling reaction

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki-Miyaura coupling reaction. / Mandai, Kyoko; Korenaga, Toshinobu; Ema, Tadashi; Sakai, Takashi; Furutani, Mitsuaki; Hashimoto, Hideki; Takada, Jun.

In: Tetrahedron Letters, Vol. 53, No. 3, 18.01.2012, p. 329-332.

Research output: Contribution to journalArticle

Mandai, Kyoko ; Korenaga, Toshinobu ; Ema, Tadashi ; Sakai, Takashi ; Furutani, Mitsuaki ; Hashimoto, Hideki ; Takada, Jun. / Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki-Miyaura coupling reaction. In: Tetrahedron Letters. 2012 ; Vol. 53, No. 3. pp. 329-332.
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