Azido(2,2′-bipyridine)(η 5-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

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8 Citations (Scopus)

Abstract

In the title compound. [Ir(C10H15)(N 3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Å. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Å] is significantly shorter than the terminal azide N-N bond [1.282 (15) Å], while the azide Ir-N-N bond angle is 116.4 (6)°.

Original languageEnglish
Pages (from-to)m488-m490
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - Mar 1 2005
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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