Azido(2,2′-bipyridine)(η 5-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

Takayoshi Suzuki

doi:10.1107/S1600536805003727

Azido(2,2′-bipyridine)(η ⁵-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

Takayoshi Suzuki

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the title compound. [Ir(C₁₀H₁₅)(N ₃)(C₁₀H₈N₂)]PF₆, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Å. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Å] is significantly shorter than the terminal azide N-N bond [1.282 (15) Å], while the azide Ir-N-N bond angle is 116.4 (6)°.

Original language	English
Pages (from-to)	m488-m490
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	3
DOIs	https://doi.org/10.1107/S1600536805003727
Publication status	Published - Mar 1 2005
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536805003727

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title = "Azido(2,2′-bipyridine)(η 5-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate",

abstract = "In the title compound. [Ir(C10H15)(N 3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) {\AA}. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) {\AA}] is significantly shorter than the terminal azide N-N bond [1.282 (15) {\AA}], while the azide Ir-N-N bond angle is 116.4 (6)°.",

author = "Takayoshi Suzuki",

year = "2005",

month = mar,

day = "1",

doi = "10.1107/S1600536805003727",

language = "English",

volume = "61",

pages = "m488--m490",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Azido(2,2′-bipyridine)(η 5-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

AU - Suzuki, Takayoshi

PY - 2005/3/1

Y1 - 2005/3/1

N2 - In the title compound. [Ir(C10H15)(N 3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Å. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Å] is significantly shorter than the terminal azide N-N bond [1.282 (15) Å], while the azide Ir-N-N bond angle is 116.4 (6)°.

AB - In the title compound. [Ir(C10H15)(N 3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Å. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Å] is significantly shorter than the terminal azide N-N bond [1.282 (15) Å], while the azide Ir-N-N bond angle is 116.4 (6)°.

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SP - m488-m490

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Azido(2,2′-bipyridine)(η ⁵-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

Abstract

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