TY - JOUR
T1 - Automatic flow kinetic-catalytic methods
AU - Henríquez, Camelia
AU - Maya, Fernando
AU - Phansi, Piyawan
AU - Abouhiat, Fatima Z.
AU - Danchana, Kaewta
AU - Cerdà, Víctor
N1 - Funding Information:
The Spanish Ministerio de Economía y Competitividad (MINECO) and the European Funds for Regional Development (FEDER) are gratefully acknowledged for financial support through Project No. CTQ2013-47461-R . The scholarships from Royal Golden Jubilee TRF-Ph.D., the Thailand Research Fund for P. Phansi is gratefully acknowledged.
Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - Kinetic-catalytic analytical methods are simple and highly sensitive strategies for chemical analysis, that rely on simple instrumentation. For that reason, they have been implemented to the quantification of a large number of chemical species such as transition metals, non-metallic anions and organic compounds. Flow techniques are presented as an efficient tool to overcome the main limitations of the kinetic-catalytic methods. Solving problems related with sample handling, the reproducible data acquisition, reproducible temperature control and the implementation of different kinetic determination methods (initial rate, fixed time and fixed measure). Herein we review the recent applications of novel approaches to perform fully automated kinetic-catalytic methods based on computer controlled flow techniques. We also describe new devices and materials such as chip-based flow injection analyzers and the use of nanoparticles to improve the performance of this class of analytical methodologies.
AB - Kinetic-catalytic analytical methods are simple and highly sensitive strategies for chemical analysis, that rely on simple instrumentation. For that reason, they have been implemented to the quantification of a large number of chemical species such as transition metals, non-metallic anions and organic compounds. Flow techniques are presented as an efficient tool to overcome the main limitations of the kinetic-catalytic methods. Solving problems related with sample handling, the reproducible data acquisition, reproducible temperature control and the implementation of different kinetic determination methods (initial rate, fixed time and fixed measure). Herein we review the recent applications of novel approaches to perform fully automated kinetic-catalytic methods based on computer controlled flow techniques. We also describe new devices and materials such as chip-based flow injection analyzers and the use of nanoparticles to improve the performance of this class of analytical methodologies.
KW - Fixed time
KW - Flow injection techniques
KW - Initial rate
KW - Kinetic-catalytic methods
KW - Miniaturization
KW - Nanoparticles
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U2 - 10.1016/j.trac.2016.08.009
DO - 10.1016/j.trac.2016.08.009
M3 - Review article
AN - SCOPUS:84988020120
SN - 0165-9936
VL - 85
SP - 33
EP - 45
JO - TrAC - Trends in Analytical Chemistry
JF - TrAC - Trends in Analytical Chemistry
ER -