Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

Masahito Murai, Shotaro Yoshida, Koji Miki, Kouichi Ohe

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.

Original languageEnglish
Pages (from-to)3366-3368
Number of pages3
JournalChemical Communications
Volume46
Issue number19
DOIs
Publication statusPublished - 2010
Externally publishedYes

Fingerprint

Stereoselectivity
Nitriles
Atoms
vinylcarbene

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds. / Murai, Masahito; Yoshida, Shotaro; Miki, Koji; Ohe, Kouichi.

In: Chemical Communications, Vol. 46, No. 19, 2010, p. 3366-3368.

Research output: Contribution to journalArticle

Murai, Masahito ; Yoshida, Shotaro ; Miki, Koji ; Ohe, Kouichi. / Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds. In: Chemical Communications. 2010 ; Vol. 46, No. 19. pp. 3366-3368.
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