Asymmetric synthesis of syn 1,2-diols via the reaction of aldehydes with chiral γ-(tetrahydropyranyloxy)allylstannanes

Yoshinori Yamamoto, Katsumi Kobayashi, Hiroshi Okano, Isao Kadota

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Abstract

Asymmetric synthesis of syn 1,2-diols 3 has been accomplished via the reaction of the chiral γ-alkoxy-substituted allylstannane 1 with aldehydes in the presence of AlCl3 or AlCl3·OEt2, followed by a five-step operation to remove the chiral auxiliary.

Original languageEnglish
Pages (from-to)7003-7005
Number of pages3
JournalJournal of Organic Chemistry
Volume57
Issue number26
Publication statusPublished - 1992
Externally publishedYes

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Aldehydes
aluminum chloride
alkoxyl radical

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Asymmetric synthesis of syn 1,2-diols via the reaction of aldehydes with chiral γ-(tetrahydropyranyloxy)allylstannanes. / Yamamoto, Yoshinori; Kobayashi, Katsumi; Okano, Hiroshi; Kadota, Isao.

In: Journal of Organic Chemistry, Vol. 57, No. 26, 1992, p. 7003-7005.

Research output: Contribution to journalArticle

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