Asymmetric Synthesis of Syn 1,2-Diols via the Reaction of Aldehydes with Chiral γ-(Tetrahydropyranyloxy)allylstannanes

Yoshinori Yamamoto, Katsumi Kobayashi, Hiroshi Okano, Isao Kadota

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Asymmetric synthesis of syn 1,2-diols 3 has been accomplished via the reaction of the chiral γ-alkoxy-substituted allylstannane 1 with aldehydes in the presence of AlCl3 or AlCl3·OEt2, followed by a five-step operation to remove the chiral auxiliary.

Original languageEnglish
Pages (from-to)7003-7005
Number of pages3
JournalJournal of Organic Chemistry
Volume57
Issue number26
DOIs
Publication statusPublished - Dec 1 1992
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Asymmetric Synthesis of Syn 1,2-Diols via the Reaction of Aldehydes with Chiral γ-(Tetrahydropyranyloxy)allylstannanes'. Together they form a unique fingerprint.

  • Cite this