Abstract
Treatment of an allylic tin-bearing chiral acetal 1a with TiCl 4-PPh3 gives the (2S, 3R) isomer 2 with high diastereoselectivity (2 : 3 = 93 : 7), whereas the reaction of an allylic silane derivative 1f affords predominantly the (2R, 3S) isomer 3 (2 : 3 = 37 : 63).
| Original language | English |
|---|---|
| Pages (from-to) | 1953-1954 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Dec 1 1994 |
| Externally published | Yes |
ASJC Scopus subject areas
- Molecular Medicine
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Kadota, I., Miura, K., & Yamamoto, Y. (1994). Asymmetric synthesis of β-alkoxycyclic ethers via the intramolecular cyclization of group 14 allyls containing chiral acetals. Journal of the Chemical Society, Chemical Communications, (17), 1953-1954. https://doi.org/10.1039/C39940001953