Asymmetric Cu(ii) catalyses for cycloaddition reactions based on π-cation or n-cation interactions

Akira Sakakura, Kazuaki Ishihara

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The rational design of small but highly functional artificial catalysts is very important for practical organic synthesis. Asymmetric Lewis acid catalyses with non-covalent secondary interactions have been developed for enantioselective reactions. This tutorial review describes the concept, design and examples of asymmetric Cu(ii) catalyses for cycloaddition reactions based on intramolecular π-cation or n-cation interactions between the copper(ii) cation and auxiliary Lewis basic sites of the chiral ligands.

Original languageEnglish
Pages (from-to)163-172
Number of pages10
JournalChemical Society Reviews
Volume40
Issue number1
DOIs
Publication statusPublished - Jan 2011
Externally publishedYes

Fingerprint

Cycloaddition
Cations
Lewis Acids
Copper
Ligands
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Asymmetric Cu(ii) catalyses for cycloaddition reactions based on π-cation or n-cation interactions. / Sakakura, Akira; Ishihara, Kazuaki.

In: Chemical Society Reviews, Vol. 40, No. 1, 01.2011, p. 163-172.

Research output: Contribution to journalArticle

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