Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities: Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties

Masaichi Saito; Tomoharu Tanikawa; Tomoyuki Tajima; Jing Dong Guo; Shigeru Nagase

doi:10.1016/j.jorganchem.2009.11.039

Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities: Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties

Masaichi Saito, Tomoharu Tanikawa, Tomoyuki Tajima, Jing Dong Guo, Shigeru Nagase

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities gave the first triphenylene derivatives whose two pairs of bay carbons are connected by two different heteroatom functionalities. Triphenyleno[1,12-bcd:4,5-b′c′d′]dithiophene, which had been only accessible through the very severe reaction conditions, was synthesized under the mild reaction conditions. Photophysical properties of newly-obtained heterolotriphenylene derivatives are discussed with theoretical calculations.

Original language	English
Pages (from-to)	1035-1041
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	695
Issue number	7
DOIs	https://doi.org/10.1016/j.jorganchem.2009.11.039
Publication status	Published - Apr 1 2010
Externally published	Yes

Keywords

Electronic absorption
Fluorescence
Silolotriphenyleno[1,12-bcd]thiophene
Stannolotriphenyleno[1,12-bcd]thiophene
Triphenyleno[1,12-bcd:4,5-b′c′d′]dithiophene

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2009.11.039

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Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities : Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties. / Saito, Masaichi; Tanikawa, Tomoharu; Tajima, Tomoyuki et al.

In: Journal of Organometallic Chemistry, Vol. 695, No. 7, 01.04.2010, p. 1035-1041.

Research output: Contribution to journal › Article › peer-review

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AU - Tanikawa, Tomoharu

AU - Tajima, Tomoyuki

AU - Guo, Jing Dong

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Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities: Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties

Abstract

Keywords

ASJC Scopus subject areas

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