Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water: halide-free oxidation directed towards a totally closed system

Koichi Mitsudo, Hiroki Kumagai, Fumiko Takabatake, Jun Kubota, Hideo Tanaka

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Electrooxidation of alcohols in water with water-soluble N-oxyl derivatives bearing a sulfonic acid group (anionic WS-TEMPOs) as a mediator proceeded to afford the corresponding ketones and aldehydes in moderate to good yields. The aqueous solution containing WS-TEMPOs could be readily recovered and reused for the electrooxidation of alcohols, thereby providing a totally closed system.

Original languageEnglish
Pages (from-to)8994-8997
Number of pages4
JournalTetrahedron Letters
Volume48
Issue number51
DOIs
Publication statusPublished - Dec 17 2007

Fingerprint

Electrooxidation
Bearings (structural)
Alcohols
Oxidation
Sulfonic Acids
Water
Ketones
Aldehydes
Derivatives
TEMPO

Keywords

  • Alcohol
  • Electrooxidation
  • N-Oxyl
  • TEMPO
  • Water
  • Water-soluble mediator

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water : halide-free oxidation directed towards a totally closed system. / Mitsudo, Koichi; Kumagai, Hiroki; Takabatake, Fumiko; Kubota, Jun; Tanaka, Hideo.

In: Tetrahedron Letters, Vol. 48, No. 51, 17.12.2007, p. 8994-8997.

Research output: Contribution to journalArticle

Mitsudo, Koichi ; Kumagai, Hiroki ; Takabatake, Fumiko ; Kubota, Jun ; Tanaka, Hideo. / Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water : halide-free oxidation directed towards a totally closed system. In: Tetrahedron Letters. 2007 ; Vol. 48, No. 51. pp. 8994-8997.
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