Anion effect on the structure of Ag2S-AgPO3 superionic glasses

E. Kartini; S. J. Kennedy; K. Itoh; T. Kamiyama; M. F. Collins; S. Suminta

doi:10.1016/j.ssi.2003.12.021

Anion effect on the structure of Ag₂S-AgPO₃ superionic glasses

E. Kartini, S. J. Kennedy, K. Itoh, T. Kamiyama, M. F. Collins, S. Suminta

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

We report on time-of-flight neutron diffraction data measured on superionic-conducting glasses (Ag₂S)_x(AgPO ₃)_{1- x} with x = 0.5 and 0.7 at room temperature via the High-Intensity Total Scattering (HIT-II) instrument at KENS and we contrast the results with AgPO₃, (AgI)_0.5(AgPO₃) _0.5 and (AgI)_0.33(Ag₂S) _0.33(AgPO₃)_0.34 glasses. The structure factor of (AgI)_0.5(AgPO₃)_0.5 shows a strong prepeak at low Q ∼ 0.8 Å^-1 in contrast to the undoped glass AgPO₃ where there is no prepeak. In the Ag₂S-AgPO ₃ system the prepeak appears only very weakly and the difference between radial distribution function (RDF) of doped and undoped glasses show peaks at 2.15, 2.55, 2.75 and 3.0 Å, corresponding to P-S, Ag-S, S-S and S-O distances, respectively. Both doped systems form superionic-conducting glasses, but the sulfide ion is largely incorporated into the phosphate tetrahedra, breaking down the corner-sharing chains into discrete PSO ₃ tetrahedra.

Original language	English
Pages (from-to)	65-71
Number of pages	7
Journal	Solid State Ionics
Volume	167
Issue number	1-2
DOIs	https://doi.org/10.1016/j.ssi.2003.12.021
Publication status	Published - Feb 12 2004
Externally published	Yes

Keywords

AgI-AgPO
AgS-AgPO
First sharp diffraction peak
Ionic conductivity
Neutron scattering
Superionic glasses

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/j.ssi.2003.12.021

Cite this

@article{13ca8f0e809049279c1fe3344d39e52e,

title = "Anion effect on the structure of Ag2S-AgPO3 superionic glasses",

abstract = "We report on time-of-flight neutron diffraction data measured on superionic-conducting glasses (Ag2S)x(AgPO 3)1- x with x = 0.5 and 0.7 at room temperature via the High-Intensity Total Scattering (HIT-II) instrument at KENS and we contrast the results with AgPO3, (AgI)0.5(AgPO3) 0.5 and (AgI)0.33(Ag2S) 0.33(AgPO3)0.34 glasses. The structure factor of (AgI)0.5(AgPO3)0.5 shows a strong prepeak at low Q ∼ 0.8 {\AA}-1 in contrast to the undoped glass AgPO3 where there is no prepeak. In the Ag2S-AgPO 3 system the prepeak appears only very weakly and the difference between radial distribution function (RDF) of doped and undoped glasses show peaks at 2.15, 2.55, 2.75 and 3.0 {\AA}, corresponding to P-S, Ag-S, S-S and S-O distances, respectively. Both doped systems form superionic-conducting glasses, but the sulfide ion is largely incorporated into the phosphate tetrahedra, breaking down the corner-sharing chains into discrete PSO 3 tetrahedra.",

keywords = "AgI-AgPO, AgS-AgPO, First sharp diffraction peak, Ionic conductivity, Neutron scattering, Superionic glasses",

author = "E. Kartini and Kennedy, {S. J.} and K. Itoh and T. Kamiyama and Collins, {M. F.} and S. Suminta",

note = "Funding Information: E.K. wishes to thank Drs. Gunandjar SU, Dr. Wuryanto, Dr. Ikram and Dr. Ridwan at BATAN for the use of the facilities; Prof. T. Fukunaga for a nice discussion; Prof. S. Ikeda is likewise thanked for his hospitality during her stay at KEK as a visiting researcher sponsored by the Ministry of Education, Culture, Sports, Science and Technology, Japan. The authors acknowledge the referee for his constructive criticism and some valuable suggestions for improving the manuscript. ",

year = "2004",

month = feb,

day = "12",

doi = "10.1016/j.ssi.2003.12.021",

language = "English",

volume = "167",

pages = "65--71",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Anion effect on the structure of Ag2S-AgPO3 superionic glasses

AU - Kartini, E.

AU - Kennedy, S. J.

AU - Itoh, K.

AU - Kamiyama, T.

AU - Collins, M. F.

AU - Suminta, S.

N1 - Funding Information: E.K. wishes to thank Drs. Gunandjar SU, Dr. Wuryanto, Dr. Ikram and Dr. Ridwan at BATAN for the use of the facilities; Prof. T. Fukunaga for a nice discussion; Prof. S. Ikeda is likewise thanked for his hospitality during her stay at KEK as a visiting researcher sponsored by the Ministry of Education, Culture, Sports, Science and Technology, Japan. The authors acknowledge the referee for his constructive criticism and some valuable suggestions for improving the manuscript.

PY - 2004/2/12

Y1 - 2004/2/12

N2 - We report on time-of-flight neutron diffraction data measured on superionic-conducting glasses (Ag2S)x(AgPO 3)1- x with x = 0.5 and 0.7 at room temperature via the High-Intensity Total Scattering (HIT-II) instrument at KENS and we contrast the results with AgPO3, (AgI)0.5(AgPO3) 0.5 and (AgI)0.33(Ag2S) 0.33(AgPO3)0.34 glasses. The structure factor of (AgI)0.5(AgPO3)0.5 shows a strong prepeak at low Q ∼ 0.8 Å-1 in contrast to the undoped glass AgPO3 where there is no prepeak. In the Ag2S-AgPO 3 system the prepeak appears only very weakly and the difference between radial distribution function (RDF) of doped and undoped glasses show peaks at 2.15, 2.55, 2.75 and 3.0 Å, corresponding to P-S, Ag-S, S-S and S-O distances, respectively. Both doped systems form superionic-conducting glasses, but the sulfide ion is largely incorporated into the phosphate tetrahedra, breaking down the corner-sharing chains into discrete PSO 3 tetrahedra.

AB - We report on time-of-flight neutron diffraction data measured on superionic-conducting glasses (Ag2S)x(AgPO 3)1- x with x = 0.5 and 0.7 at room temperature via the High-Intensity Total Scattering (HIT-II) instrument at KENS and we contrast the results with AgPO3, (AgI)0.5(AgPO3) 0.5 and (AgI)0.33(Ag2S) 0.33(AgPO3)0.34 glasses. The structure factor of (AgI)0.5(AgPO3)0.5 shows a strong prepeak at low Q ∼ 0.8 Å-1 in contrast to the undoped glass AgPO3 where there is no prepeak. In the Ag2S-AgPO 3 system the prepeak appears only very weakly and the difference between radial distribution function (RDF) of doped and undoped glasses show peaks at 2.15, 2.55, 2.75 and 3.0 Å, corresponding to P-S, Ag-S, S-S and S-O distances, respectively. Both doped systems form superionic-conducting glasses, but the sulfide ion is largely incorporated into the phosphate tetrahedra, breaking down the corner-sharing chains into discrete PSO 3 tetrahedra.

KW - AgI-AgPO

KW - AgS-AgPO

KW - First sharp diffraction peak

KW - Ionic conductivity

KW - Neutron scattering

KW - Superionic glasses

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U2 - 10.1016/j.ssi.2003.12.021

DO - 10.1016/j.ssi.2003.12.021

M3 - Article

AN - SCOPUS:1642329198

SN - 0167-2738

VL - 167

SP - 65

EP - 71

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-2

ER -