Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using 19F very fast magic angle spinning nuclear magnetic resonance

Kazuma Gotoh, Kazuyuki Takeda, Michael M. Lerner, Yoshimi Sueishi, Shinpei Maruyama, Atsushi Goto, Masataka Tansho, Shinobu Ohki, Kenjiro Hashi, Tadashi Shimizu, Hiroyuki Ishida

Research output: Contribution to journalArticle

Abstract

F atoms bonding to paramagnetic/conductive graphene layers in accepter-type graphite intercalation compounds (GICs) are analyzed using very fast magic angle spinning nuclear magnetic resonance, which is applied for the first time on 19F nuclei to investigate paramagnetic materials. In the bis(trifluoromethylsulfonyl)imide(TFSI)-doped GIC, C-F bonds between fluorine atoms and graphene layers conform to a weak bonding of F to the graphene sheets. TFSI anions intercalated in the GIC do not show overall molecular motion; even at room temperature only the CF3 groups rotate.

Original languageEnglish
Pages (from-to)4064-4066
Number of pages3
JournalCarbon
Volume49
Issue number12
DOIs
Publication statusPublished - Oct 2011

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Imides
Intercalation compounds
Magic angle spinning
Graphite
Graphene
Nuclear magnetic resonance
Paramagnetic materials
Atoms
Fluorine
Anions
Negative ions
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using 19F very fast magic angle spinning nuclear magnetic resonance. / Gotoh, Kazuma; Takeda, Kazuyuki; Lerner, Michael M.; Sueishi, Yoshimi; Maruyama, Shinpei; Goto, Atsushi; Tansho, Masataka; Ohki, Shinobu; Hashi, Kenjiro; Shimizu, Tadashi; Ishida, Hiroyuki.

In: Carbon, Vol. 49, No. 12, 10.2011, p. 4064-4066.

Research output: Contribution to journalArticle

Gotoh, Kazuma ; Takeda, Kazuyuki ; Lerner, Michael M. ; Sueishi, Yoshimi ; Maruyama, Shinpei ; Goto, Atsushi ; Tansho, Masataka ; Ohki, Shinobu ; Hashi, Kenjiro ; Shimizu, Tadashi ; Ishida, Hiroyuki. / Analysis of bis(trifluoromethylsulfonyl)imide-doped paramagnetic graphite intercalation compound using 19F very fast magic angle spinning nuclear magnetic resonance. In: Carbon. 2011 ; Vol. 49, No. 12. pp. 4064-4066.
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