An NMR study on the dynamic behavior of triethylamine included in AFI crystals - Influence of acid sites on the motional state of triethylamine molecules

Kazuma Gotoh, Shin'ichi Ishimaru, Ryuichi Ikeda

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The 1H NMR spin-lattice relaxation times (T1) of triethylamine (TEA) molecules included in five kinds of AFI crystals with different concentrations of Si atoms in the wall were measured. The temperature and Larmor frequency dependences of T1 were well explained by introducing a distributed motional correlation time (τ) for the pseudo-C3 TEA reorientation. An obtained linear decrease in the τ distribution width with an increase of the Si concentration, i.e., the number of Brønsted acid sites, was shown to be related to the orientations of TEA molecules in channels.

Original languageEnglish
Pages (from-to)1723-1727
Number of pages5
JournalBulletin of the Chemical Society of Japan
Volume76
Issue number9
DOIs
Publication statusPublished - Sep 1 2003
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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