An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols

Hideo Tanaka; Yusuke Kawakami; Kentaro Goto; Manabu Kuroboshi

doi:10.1016/S0040-4039(00)01979-1

An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols

Hideo Tanaka, Yusuke Kawakami, Kentaro Goto, Manabu Kuroboshi

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active γ-lactone.

Original language	English
Pages (from-to)	445-448
Number of pages	4
Journal	Tetrahedron Letters
Volume	42
Issue number	3
DOIs	https://doi.org/10.1016/S0040-4039(00)01979-1
Publication status	Published - Jan 15 2001

Keywords

Alcohols
Electrochemistry
Enantioselective
Oxidation

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)01979-1

Cite this

@article{880813971e2a43118c60a82b73ae3495,

title = "An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols",

abstract = "N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active γ-lactone.",

keywords = "Alcohols, Electrochemistry, Enantioselective, Oxidation",

author = "Hideo Tanaka and Yusuke Kawakami and Kentaro Goto and Manabu Kuroboshi",

year = "2001",

month = jan,

day = "15",

doi = "10.1016/S0040-4039(00)01979-1",

language = "English",

volume = "42",

pages = "445--448",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "3",

}

TY - JOUR

T1 - An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols

AU - Tanaka, Hideo

AU - Kawakami, Yusuke

AU - Goto, Kentaro

AU - Kuroboshi, Manabu

PY - 2001/1/15

Y1 - 2001/1/15

N2 - N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active γ-lactone.

AB - N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active γ-lactone.

KW - Alcohols

KW - Electrochemistry

KW - Enantioselective

KW - Oxidation

UR - http://www.scopus.com/inward/record.url?scp=0035862651&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035862651&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)01979-1

DO - 10.1016/S0040-4039(00)01979-1

M3 - Article

AN - SCOPUS:0035862651

SN - 0040-4039

VL - 42

SP - 445

EP - 448

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 3

ER -

An aqueous silica gel disperse electrolysis system. N-Oxyl-mediated electrooxidation of alcohols

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this