An alternative synthetic route to 3H-azepines: Thermal isomerization of 2,4-and 3,5-di-t-butyl-3a,5a-dihydro-3H-cyclobuta[b]pyrroles

Kyosuke Satake, H. Saitoh, M. Kimura, S. Morosawa

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Di-t-butyl derivatives of 3a,5a-dihydro-3H-cyclobuta[b]pyrroles, synthesized from photoisomers of 1H-azepine derivatives (Dewar azepines), isomerized thermally to 3H-azepines.

Original languageEnglish
Pages (from-to)1121-1123
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number16
DOIs
Publication statusPublished - 1988

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Azepines
Pyrroles
Isomerization
Hot Temperature
Derivatives
Dewars

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

An alternative synthetic route to 3H-azepines : Thermal isomerization of 2,4-and 3,5-di-t-butyl-3a,5a-dihydro-3H-cyclobuta[b]pyrroles. / Satake, Kyosuke; Saitoh, H.; Kimura, M.; Morosawa, S.

In: Journal of the Chemical Society, Chemical Communications, No. 16, 1988, p. 1121-1123.

Research output: Contribution to journalArticle

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abstract = "Di-t-butyl derivatives of 3a,5a-dihydro-3H-cyclobuta[b]pyrroles, synthesized from photoisomers of 1H-azepine derivatives (Dewar azepines), isomerized thermally to 3H-azepines.",
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