TY - JOUR
T1 - An 1H NMR Study on the Cationic Motion in Solid tert-Butylammonium Chloride and Bromide
AU - Ishida, Hiroyuki
AU - Inada, Syuichi
AU - Hayama, Naomi
AU - Nakamura, Daiyu
AU - Ikeda, Ryuichi
N1 - Funding Information:
ments. This work was supported by a Grant-in-aid for Scientific Research No. 02740232 from the Ministry of Education, Science and Culture, Japan.
PY - 1991/3/1
Y1 - 1991/3/1
N2 - The 1H spin-lattice relaxation time (T1) in solid (CD3)3CNH3C1 and (CD3)3CNH3Br was measured above room temperature and the motional parameters for the reorientation of the NH†3 groups were determined. The '1-1 NMR absorptions measured in the same temperature range for (CH3)3CNH3C1 and (CH3)3CNH3Br indicate the presence of superimposed several cationic motions commonly taking place in both compounds. From X-ray powder patterns taken at room temperature, the bromide was found to be isomorphous with the chloride.
AB - The 1H spin-lattice relaxation time (T1) in solid (CD3)3CNH3C1 and (CD3)3CNH3Br was measured above room temperature and the motional parameters for the reorientation of the NH†3 groups were determined. The '1-1 NMR absorptions measured in the same temperature range for (CH3)3CNH3C1 and (CH3)3CNH3Br indicate the presence of superimposed several cationic motions commonly taking place in both compounds. From X-ray powder patterns taken at room temperature, the bromide was found to be isomorphous with the chloride.
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U2 - 10.1515/zna-1991-0309
DO - 10.1515/zna-1991-0309
M3 - Article
AN - SCOPUS:0040040501
SN - 0932-0784
VL - 46
SP - 265
EP - 268
JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
IS - 3
ER -