An 1H NMR Study on the Cationic Motion in Solid tert-Butylammonium Chloride and Bromide

Hiroyuki Ishida, Syuichi Inada, Naomi Hayama, Daiyu Nakamura, Ryuichi Ikeda

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The 1H spin-lattice relaxation time (T1) in solid (CD3)3CNH3C1 and (CD3)3CNH3Br was measured above room temperature and the motional parameters for the reorientation of the NH†3 groups were determined. The '1-1 NMR absorptions measured in the same temperature range for (CH3)3CNH3C1 and (CH3)3CNH3Br indicate the presence of superimposed several cationic motions commonly taking place in both compounds. From X-ray powder patterns taken at room temperature, the bromide was found to be isomorphous with the chloride.

Original languageEnglish
Pages (from-to)265-268
Number of pages4
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume46
Issue number3
DOIs
Publication statusPublished - Mar 1 1991

Fingerprint

Bromides
Chlorides
bromides
chlorides
Nuclear magnetic resonance
nuclear magnetic resonance
Motion
room temperature
spin-lattice relaxation
retraining
Spin-lattice relaxation
relaxation time
Relaxation Time
Powder
Powders
Relaxation time
Temperature
Absorption
X rays
x rays

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Mathematical Physics
  • Physics and Astronomy(all)

Cite this

An 1H NMR Study on the Cationic Motion in Solid tert-Butylammonium Chloride and Bromide. / Ishida, Hiroyuki; Inada, Syuichi; Hayama, Naomi; Nakamura, Daiyu; Ikeda, Ryuichi.

In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 46, No. 3, 01.03.1991, p. 265-268.

Research output: Contribution to journalArticle

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