Alkynylboron compounds in organic synthesis

    Research output: Contribution to journalReview articlepeer-review

    30 Citations (Scopus)

    Abstract

    Alkynylboron compounds, consisting of alkynyl and boron moieties, can be categorized according to the substituents on the boron atom, such as alkynylboranes, -boronates, and -borates. In this review, the synthesis and reactions of alkynylboron compounds are systematically introduced. Alkynylpinacolatoboranes and alkynyltrifluoroborates are the most widely utilized classes in organic reactions, owing to their stability and ease of handling. Other alkynylboron compounds have also been developed as convenient substrates for various organic reactions. Thanks to the dedication of many chemists in this field, great advances of facile synthesis and wide utilization of alkynylboron compounds have been made with these versatile building blocks for diverse structures in organic synthesis.

    Original languageEnglish
    Pages (from-to)3-16
    Number of pages14
    JournalJournal of Organometallic Chemistry
    Volume721-722
    DOIs
    Publication statusPublished - Dec 15 2012

    Keywords

    • Addition reactions
    • Alkynylboron compounds
    • Cross-coupling
    • Cycloaddition reactions
    • Zirconium

    ASJC Scopus subject areas

    • Biochemistry
    • Physical and Theoretical Chemistry
    • Organic Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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