Alkoxy-directed insertion of carbon-carbon double bonds into tantalum-alkyne complexes. Chemo- and stereoselective addition of alkenyl groups to olefins

Kazuhiko Takai, Masashi Yamada, Hidetoshi Odaka, Kiitiro Utimoto

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Chemo- and stereoselective addition of alkenyl groups at terminal positions of olefins is accomplished by the reaction between tantalum-alkyne complexes and terminal olefins having adjacent hydroxyl groups.

Original languageEnglish
Pages (from-to)5852-5853
Number of pages2
JournalJournal of Organic Chemistry
Volume59
Issue number20
Publication statusPublished - 1994

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Tantalum
Alkynes
Alkenes
Carbon
Hydroxyl Radical
alkoxyl radical

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Alkoxy-directed insertion of carbon-carbon double bonds into tantalum-alkyne complexes. Chemo- and stereoselective addition of alkenyl groups to olefins. / Takai, Kazuhiko; Yamada, Masashi; Odaka, Hidetoshi; Utimoto, Kiitiro.

In: Journal of Organic Chemistry, Vol. 59, No. 20, 1994, p. 5852-5853.

Research output: Contribution to journalArticle

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abstract = "Chemo- and stereoselective addition of alkenyl groups at terminal positions of olefins is accomplished by the reaction between tantalum-alkyne complexes and terminal olefins having adjacent hydroxyl groups.",
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AU - Takai, Kazuhiko

AU - Yamada, Masashi

AU - Odaka, Hidetoshi

AU - Utimoto, Kiitiro

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