Aliphatic claisen rearrangement promoted by organoaluminium compounds

Kazuhiko Takai, Ichiro Mori, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Treatment of allyl vinyl ether derivatives with organoaluminiumamphoteric reagent, R3Al or R2AlSPn, results in the title reaction at room temperature under uptake of R, H, or SPh as a nucleophile on the aldehydic carbon.

Original languageEnglish
Pages (from-to)3985-3988
Number of pages4
JournalTetrahedron Letters
Volume22
Issue number40
DOIs
Publication statusPublished - 1981
Externally publishedYes

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Nucleophiles
Carbon
Derivatives
Temperature
vinyl ether

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Aliphatic claisen rearrangement promoted by organoaluminium compounds. / Takai, Kazuhiko; Mori, Ichiro; Oshima, Koichiro; Nozaki, Hitosi.

In: Tetrahedron Letters, Vol. 22, No. 40, 1981, p. 3985-3988.

Research output: Contribution to journalArticle

Takai, Kazuhiko ; Mori, Ichiro ; Oshima, Koichiro ; Nozaki, Hitosi. / Aliphatic claisen rearrangement promoted by organoaluminium compounds. In: Tetrahedron Letters. 1981 ; Vol. 22, No. 40. pp. 3985-3988.
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