Aldol-type reaction of a 4-pyrone: a straightforward approach to 4-pyrone-containing natural products

Tetsuya Sengoku, Takuma Takemura, Emi Fukasawa, Ichiro Hayakawa, Hideo Kigoshi

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A straightforward approach to 4-pyrone-containing natural products has been developed, which includes an aldol-type reaction between 2,6-diethyl-3,5-dimethyl-4-pyrone and aldehydes. The counter cation of the carbanion of the pyrone was found to play an important role in this reaction.

Original languageEnglish
Pages (from-to)325-328
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number3
DOIs
Publication statusPublished - Jan 21 2009
Externally publishedYes

Fingerprint

Pyrones
Biological Products
Aldehydes
Cations
3-hydroxybutanal

Keywords

  • 4-Pyrone-containing natural product
  • Aldol-type reaction
  • Counter cation

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Aldol-type reaction of a 4-pyrone : a straightforward approach to 4-pyrone-containing natural products. / Sengoku, Tetsuya; Takemura, Takuma; Fukasawa, Emi; Hayakawa, Ichiro; Kigoshi, Hideo.

In: Tetrahedron Letters, Vol. 50, No. 3, 21.01.2009, p. 325-328.

Research output: Contribution to journalArticle

Sengoku, Tetsuya ; Takemura, Takuma ; Fukasawa, Emi ; Hayakawa, Ichiro ; Kigoshi, Hideo. / Aldol-type reaction of a 4-pyrone : a straightforward approach to 4-pyrone-containing natural products. In: Tetrahedron Letters. 2009 ; Vol. 50, No. 3. pp. 325-328.
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