Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent

Kazuhiko Takai; Tooru Kuroda; Shigeki Nakatsukasa; Koichiro Oshima; Hitosi Nozakil

doi:10.1016/S0040-4039(01)80894-7

Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent

Kazuhiko Takai, Tooru Kuroda, Shigeki Nakatsukasa, Koichiro Oshima, Hitosi Nozakil

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

Alkynyl halides are reduced by chromium(II) chloride in DMF to give unisolable alkynylchromium compounds which add selectively to an aldehyde moiety without affecting the coexisting ketone group of the substrate.

Original language	English
Pages (from-to)	5585-5588
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(01)80894-7
Publication status	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)80894-7

Cite this

@article{deb772ea84ac4e988046b99b84565874,

title = "Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent",

abstract = "Alkynyl halides are reduced by chromium(II) chloride in DMF to give unisolable alkynylchromium compounds which add selectively to an aldehyde moiety without affecting the coexisting ketone group of the substrate.",

author = "Kazuhiko Takai and Tooru Kuroda and Shigeki Nakatsukasa and Koichiro Oshima and Hitosi Nozakil",

year = "1985",

doi = "10.1016/S0040-4039(01)80894-7",

language = "English",

volume = "26",

pages = "5585--5588",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "45",

}

TY - JOUR

T1 - Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent

AU - Takai, Kazuhiko

AU - Kuroda, Tooru

AU - Nakatsukasa, Shigeki

AU - Oshima, Koichiro

AU - Nozakil, Hitosi

PY - 1985

Y1 - 1985

N2 - Alkynyl halides are reduced by chromium(II) chloride in DMF to give unisolable alkynylchromium compounds which add selectively to an aldehyde moiety without affecting the coexisting ketone group of the substrate.

AB - Alkynyl halides are reduced by chromium(II) chloride in DMF to give unisolable alkynylchromium compounds which add selectively to an aldehyde moiety without affecting the coexisting ketone group of the substrate.

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UR - http://www.scopus.com/inward/citedby.url?scp=0000786794&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(01)80894-7

DO - 10.1016/S0040-4039(01)80894-7

M3 - Article

AN - SCOPUS:0000786794

SN - 0040-4039

VL - 26

SP - 5585

EP - 5588

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent

Abstract

ASJC Scopus subject areas

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