Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems

Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.

Original languageEnglish
Pages (from-to)299-303
Number of pages5
JournalJournal of Fluorine Chemistry
Volume39
Issue number2
DOIs
Publication statusPublished - 1988
Externally publishedYes

Fingerprint

Addition reactions
Tin
iodide
Iodides
tin
iodides
Carbon
Salts
Metals
salts
salt
carbon
metal
metals
alkene
Alkenes
Aluminum
Silver
Heating
alkenes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems. / Kuroboshi, Manabu; Ishihara, Takashi.

In: Journal of Fluorine Chemistry, Vol. 39, No. 2, 1988, p. 299-303.

Research output: Contribution to journalArticle

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