Addition reactions of F-alkyl iodides to carbon-carbon double bonds promoted by metallic tin(0)-metal salt systems

Manabu Kuroboshi, Takashi Ishihara

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

F-alkyl iodides readily reacted with a variety of alkenes in methanol at room temperature under the influence of metallic tin(0)-silver(I) acetate of metallic tin(0)-copper(I) chloride to afford the corresponding addition products, F- alkylated iodides, in good to excellent yields. This addition reaction was also promoted by the use of a metallic tin(0)- aluminium(0) reagent, though gentle heating was necessary for allowing the reaction to proceed.

Original languageEnglish
Pages (from-to)299-303
Number of pages5
JournalJournal of Fluorine Chemistry
Volume39
Issue number2
DOIs
Publication statusPublished - May 1988
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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