Addition of n-acyliminium ion pools to alkenes having a nucleophilic moiety: Integration of intermolecular and intramolecular reactions

Yosuke Ashikari, Yohei Kiuchi, Tomoya Takeuchi, Koji Ueoka, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reaction of electrochemically generated N-acyliminium ion pools with alkenes bearing a heteroatom nucleophilic functionality such as a hydroxy group, a carboxy group, and an oxime moiety led to intermolecular carboncarbon bond formation followed by intramolecular carbonheteroatom bond formation to give the corresponding heterocyclic compounds such as cyclic ethers, lactones, and 2-isoxazolines, respectively.

Original languageEnglish
Pages (from-to)210-212
Number of pages3
JournalChemistry Letters
Volume43
Issue number2
DOIs
Publication statusPublished - Feb 11 2014
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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