Addition of n-acyliminium ion pools to alkenes having a nucleophilic moiety: Integration of intermolecular and intramolecular reactions

Yosuke Ashikari, Yohei Kiuchi, Tomoya Takeuchi, Koji Ueoka, Seiji Suga, Jun Ichi Yoshida

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The reaction of electrochemically generated N-acyliminium ion pools with alkenes bearing a heteroatom nucleophilic functionality such as a hydroxy group, a carboxy group, and an oxime moiety led to intermolecular carboncarbon bond formation followed by intramolecular carbonheteroatom bond formation to give the corresponding heterocyclic compounds such as cyclic ethers, lactones, and 2-isoxazolines, respectively.

Original languageEnglish
Pages (from-to)210-212
Number of pages3
JournalChemistry Letters
Volume43
Issue number2
DOIs
Publication statusPublished - 2014
Externally publishedYes

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Bearings (structural)
Cyclic Ethers
Heterocyclic Compounds
Oximes
Alkenes
Lactones
Ions

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Addition of n-acyliminium ion pools to alkenes having a nucleophilic moiety : Integration of intermolecular and intramolecular reactions. / Ashikari, Yosuke; Kiuchi, Yohei; Takeuchi, Tomoya; Ueoka, Koji; Suga, Seiji; Yoshida, Jun Ichi.

In: Chemistry Letters, Vol. 43, No. 2, 2014, p. 210-212.

Research output: Contribution to journalArticle

Ashikari, Yosuke ; Kiuchi, Yohei ; Takeuchi, Tomoya ; Ueoka, Koji ; Suga, Seiji ; Yoshida, Jun Ichi. / Addition of n-acyliminium ion pools to alkenes having a nucleophilic moiety : Integration of intermolecular and intramolecular reactions. In: Chemistry Letters. 2014 ; Vol. 43, No. 2. pp. 210-212.
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