Addition of ArSSAr to dienes via intramolecular C-C bond formation initiated by a catalytic amount of ArS+

Kouichi Matsumoto; Shunsuke Fujie; Seiji Suga; Toshiki Nokami; Jun Ichi Yoshida

doi:10.1039/b910821a

Addition of ArSSAr to dienes via intramolecular C-C bond formation initiated by a catalytic amount of ArS⁺

Kouichi Matsumoto, Shunsuke Fujie, Seiji Suga, Toshiki Nokami, Jun Ichi Yoshida

Okayama University

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A catalytic amount of electrochemically generated "ArS ⁺" ("ArS⁺" = ArS(ArSSAr)⁺) initiates a cation chain reaction of dienes that involves the addition of ArSSAr associated with stereoselective intramolecular carbon-carbon bond formation, and the direct (in-cell) electrolysis of a mixture of a diene and ArSSAr with a catalytic amount of electricity also effectively initiates the reaction.

Original language	English
Pages (from-to)	5448-5450
Number of pages	3
Journal	Chemical Communications
Issue number	36
DOIs	https://doi.org/10.1039/b910821a
Publication status	Published - 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Matsumoto, Kouichi

AU - Fujie, Shunsuke

AU - Suga, Seiji

AU - Nokami, Toshiki

AU - Yoshida, Jun Ichi

PY - 2009

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AB - A catalytic amount of electrochemically generated "ArS +" ("ArS+" = ArS(ArSSAr)+) initiates a cation chain reaction of dienes that involves the addition of ArSSAr associated with stereoselective intramolecular carbon-carbon bond formation, and the direct (in-cell) electrolysis of a mixture of a diene and ArSSAr with a catalytic amount of electricity also effectively initiates the reaction.

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