Acyclic stereoselection. 32. Synthesis and characterization of the diastereomeric (4S)-pentane-1,2,3,4-tetrols

Kazuhiko Takai, Clayton H. Heathcock

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Abstract

The stereochemistry of the reaction of the lithium enolate of ester 1 and ketene acetal 3 with aldehyde 2 has been investigated. The diastereomeric (4S)-pentane-1,2,3,4-tetrols and their corresponding tetraacetate esters have been prepared and characterized.

Original languageEnglish
Pages (from-to)3247-3251
Number of pages5
JournalJournal of Organic Chemistry
Volume50
Issue number18
Publication statusPublished - 1985
Externally publishedYes

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Esters
Acetals
Stereochemistry
Lithium
Aldehydes
pentane
ketene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Acyclic stereoselection. 32. Synthesis and characterization of the diastereomeric (4S)-pentane-1,2,3,4-tetrols. / Takai, Kazuhiko; Heathcock, Clayton H.

In: Journal of Organic Chemistry, Vol. 50, No. 18, 1985, p. 3247-3251.

Research output: Contribution to journalArticle

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