Acyclic Stereoselection. 32. Synthesis and Characterization of the Diastereomeric (4S)-Pentane-1,2,3,4-tetrols

Kazuhiko Takai; Clayton H. Heathcock

doi:10.1021/jo00218a001

Acyclic Stereoselection. 32. Synthesis and Characterization of the Diastereomeric (4S)-Pentane-1,2,3,4-tetrols

Kazuhiko Takai, Clayton H. Heathcock

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Abstract

The stereochemistry of the reaction of the lithium enolate of ester 1 and ketene acetal 3 with aldehyde 2 has been investigated. The diastereomeric (4S)-pentane-1,2,3,4-tetrols and their corresponding tetraacetate esters have been prepared and characterized.

Original language	English
Pages (from-to)	3247-3251
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	50
Issue number	18
DOIs	https://doi.org/10.1021/jo00218a001
Publication status	Published - Jan 1 1985

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ASJC Scopus subject areas

Organic Chemistry

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Takai, K., & Heathcock, C. H. (1985). Acyclic Stereoselection. 32. Synthesis and Characterization of the Diastereomeric (4S)-Pentane-1,2,3,4-tetrols. Journal of Organic Chemistry, 50(18), 3247-3251. https://doi.org/10.1021/jo00218a001

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10.1021/jo00218a001