TY - JOUR
T1 - Activation of manganese metal with a catalytic amount of lead and Me3SiCl and its application to organic synthesis
AU - Takai, Kazuhiko
PY - 2002/11
Y1 - 2002/11
N2 - The reducing ability of manganese metal can be utilized effectively by treatment with a catalytic amount of PbCli and Me3SiCl. This article discusses the following specific themes using the activated manganese metal as a reductant. 1) Generation of alkyl radicals and their trapping with α β-unsaturated esters. 2) Three-component coupling reactions of alkyl iodides, electron-deficient olefins, and carbonyl compounds based on the concept of sequential generation of a radical and anionic species. 3) Sequential 1,4-addition and Claisen rearrangement. 4) Generation of non-stabilized carbonyl ylides. 5) Selective reduction of iod-oform and its application to the synthesis of alkenylsilanes.
AB - The reducing ability of manganese metal can be utilized effectively by treatment with a catalytic amount of PbCli and Me3SiCl. This article discusses the following specific themes using the activated manganese metal as a reductant. 1) Generation of alkyl radicals and their trapping with α β-unsaturated esters. 2) Three-component coupling reactions of alkyl iodides, electron-deficient olefins, and carbonyl compounds based on the concept of sequential generation of a radical and anionic species. 3) Sequential 1,4-addition and Claisen rearrangement. 4) Generation of non-stabilized carbonyl ylides. 5) Selective reduction of iod-oform and its application to the synthesis of alkenylsilanes.
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U2 - 10.5059/yukigoseikyokaishi.60.1055
DO - 10.5059/yukigoseikyokaishi.60.1055
M3 - Article
AN - SCOPUS:0036880141
VL - 60
SP - 1055
EP - 1062
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 11 SPEC.
ER -