A unique chelating effect of Sc(OTf)3 to organofluorine compounds

Hiroshi Kajiro, Atsunori Mori, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position β to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.

Original languageEnglish
Pages (from-to)459-460
Number of pages2
JournalChemistry Letters
Issue number6
Publication statusPublished - 1999
Externally publishedYes

Fingerprint

Scandium
Fluorine
Chelation
Acetates
Bearings (structural)
Atoms
Hydrolysis
scandium triflate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A unique chelating effect of Sc(OTf)3 to organofluorine compounds. / Kajiro, Hiroshi; Mori, Atsunori; Nishihara, Yasushi; Hiyama, Tamejiro.

In: Chemistry Letters, No. 6, 1999, p. 459-460.

Research output: Contribution to journalArticle

Kajiro, Hiroshi ; Mori, Atsunori ; Nishihara, Yasushi ; Hiyama, Tamejiro. / A unique chelating effect of Sc(OTf)3 to organofluorine compounds. In: Chemistry Letters. 1999 ; No. 6. pp. 459-460.
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