Abstract
A tripodal hexadentate ligand containing three imidazole groups gives spin-crossover iron complexes in both the +II and the +III oxidation states. The tetrafluoroborate salt of the Fe(II) complex shows a gradual spin transition in the temperature range 110-270 K. The corresponding Fe(III) complex shows a spin transition above 150 K, and at 300 K ca. 87% of the Fe(III) ion is in the high-spin state.
| Original language | English |
|---|---|
| Pages (from-to) | 350-351 |
| Number of pages | 2 |
| Journal | Chemistry Letters |
| Volume | 33 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 1 2004 |
ASJC Scopus subject areas
- Chemistry(all)
Fingerprint Dive into the research topics of 'A tripodal ligand containing three imidazole groups inducing spin crossover in both Fe(II) and Fe(III) complexes; structures and spin crossover behaviors of the complexes'. Together they form a unique fingerprint.
Cite this
Ohta, H., Sunatsuki, Y., Kojima, M., Iijima, S., Akashi, H., & Matsumoto, N. (2004). A tripodal ligand containing three imidazole groups inducing spin crossover in both Fe(II) and Fe(III) complexes; structures and spin crossover behaviors of the complexes. Chemistry Letters, 33(3), 350-351. https://doi.org/10.1246/cl.2004.350