A trinuclear chromium(iii) chlorocarbyne

Takashi Kurogi, Keiichi Irifune, Takahiro Enoki, Kazuhiko Takai

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Reduction of CCl4 by CrCl2 in THF afforded a trinuclear chromium(iii) carbyne [CrCl(thf)2]3(μ3-CCl)(μ-Cl)3. The chlorocarbyne complex reacted with aldehydes to afford chloroallylic alcohols and terminal alkynes. The mechanistic study proposed two competitive pathways via an α-chlorovinyl intermediate.

Original languageEnglish
Pages (from-to)5199-5202
Number of pages4
JournalChemical Communications
Volume57
Issue number42
DOIs
Publication statusPublished - May 25 2021

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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