Abstract
A stable sulfonato complex, (2-aminoethanesulfonato-N,O)bis(ethylenediamine-N,N′)cobalt(III) perchlorate, [Co(C2H6NO3S)(C2H8N 2)2](ClO4)2, was prepared by oxidation of [Co{OS(O)CH2CH2NH2-N,O}(en)2] 2+ (en = NH2CH2CH2NH2) in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography and the absolute configuration of the slower eluted (-)589-isomer was determined by X-ray analysis to be Δ.
| Original language | English |
|---|---|
| Pages (from-to) | 1761-1762 |
| Number of pages | 2 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 53 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Dec 15 1997 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
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Murata, M., Kojima, M., Kita, M., Kashino, S., & Yoshikawa, Y. (1997). A stable sulfonato-cobalt(III) complex: Δ-[Co{OS(O)2CH2CH2NH 2-N,O}(en)2]-(ClO4)2. Acta Crystallographica Section C: Crystal Structure Communications, 53(12), 1761-1762. https://doi.org/10.1107/S0108270197010032