TY - JOUR
T1 - A stable sulfonato-cobalt(III) complex
T2 - Δ-[Co{OS(O)2CH2CH2NH 2-N,O}(en)2]-(ClO4)2
AU - Murata, Mayumi
AU - Kojima, Masaaki
AU - Kita, Masakazu
AU - Kashino, Setsuo
AU - Yoshikawa, Yuzo
PY - 1997/12/15
Y1 - 1997/12/15
N2 - A stable sulfonato complex, (2-aminoethanesulfonato-N,O)bis(ethylenediamine-N,N′)cobalt(III) perchlorate, [Co(C2H6NO3S)(C2H8N 2)2](ClO4)2, was prepared by oxidation of [Co{OS(O)CH2CH2NH2-N,O}(en)2] 2+ (en = NH2CH2CH2NH2) in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography and the absolute configuration of the slower eluted (-)589-isomer was determined by X-ray analysis to be Δ.
AB - A stable sulfonato complex, (2-aminoethanesulfonato-N,O)bis(ethylenediamine-N,N′)cobalt(III) perchlorate, [Co(C2H6NO3S)(C2H8N 2)2](ClO4)2, was prepared by oxidation of [Co{OS(O)CH2CH2NH2-N,O}(en)2] 2+ (en = NH2CH2CH2NH2) in acid media. This sulfonato complex was resolved by SP-Sephadex column chromatography and the absolute configuration of the slower eluted (-)589-isomer was determined by X-ray analysis to be Δ.
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U2 - 10.1107/S0108270197010032
DO - 10.1107/S0108270197010032
M3 - Article
AN - SCOPUS:0031336305
VL - 53
SP - 1761
EP - 1762
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 12
ER -